Page 148 - 201811

·1934· 精细化工 FINE CHEMICALS 第 35 卷

参考文献：
[1] Dufresne A, Castano J. Polysaccharide nanomaterial reinforced
starch nanocomposites: a review[J]. Starch-Stärke, 2016, 68(1/2):
1-19.
[2] Wang Kangjian (王康建), Dan Weihua (但卫华), Guan Linbo (关林
波 ), et al. Application of modified starch in leather-making
industry[J]. Leather Science and Engineering (皮革科学与工程),
2007, 17(6): 36-39.
[3] Jayakumar G C, Kanth S V, Rao J R, et al. A molecular level
investigation of dialdehyde starch interaction with collagen for
Eco-friendly stabilization[J]. Journal of the American Leather
Chemists Association, 2015, 110(5): 145-151.
[4] Kanth S V, Madhan B, Rao J R, et al. Studies on the stabilization of
collagen using dialdehyde starch: Part I. Effect of autoclaving on
dialdehyde starch[J].Journal of the American Leather Chemists
Association, 2006, 101(12): 444-453.
[5] Yuan Hongchang (袁鸿昌), Yang Mao (杨茂), Shan Zhihua (单志
华), et al. Advanced modification of soluble starch and its filling of
wet-chromed goat skin[J]. Fine Chemials(精细化工), 2014, 31(2):
229-233.
[6] Du X S, Chen H, Dai R, et al. Preparation and application of
denatured starches[J]. Journal of the Society of Leather
Technologises and Chemists, 2012, 96(5): 189-194.

[7] Wang Xuechuan (王学川), Li Feihu (李飞虎), Qiang Taotao (强涛
a—对照；b—WO 4；c—VO 3；d—Cu-Fe 涛), et al. The preparation of high-oxidized starch and its properties
of tannage[J]. Leather Science and Engineering(皮革科学与工程),
图 7 不同氧化淀粉配体对锆鞣革纤维分散程度的影响 2013, 23(2): 5-8.
Fig. 7 Effects of oxidized starch ligand on the fiber [8] Wang Xuechuan (王学川), Li Feihu (李飞虎), Ren Longfang (任龙
dispersion of Zr- tanned leather 芳), et al. Preparation method of aluminum-oxidized starch complex
tanning agent: CN102747173A [P]. 2012-10-24.
[9] Yu Y, Wang Y N, Ding W, et al. Preparation of highly-oxidized starch
using hydrogen peroxide and its application as a novel ligand for
分子质量过大（M w =465095），形成的锆配合物较难 zirconium tanning of leather[J]. Carbohydrate Polymers, 2017, 174:
渗透至皮革内部，锆分布不均且结合量低，最终导 823-829.
[10] Parovuori P, Hamunen A, Forssell P, et al. Oxidation of potato starch
致鞣制效果不佳。需要注意的是，WO 4 组氧化淀粉 by hydrogen peroxide[J]. Starch-Stärke, 1995, 47(1): 19-23.
[11] Floor M, Schenk K M, Kieboom A P G, et al. Oxidation of
配体氧化度比对照组更高，但其鞣制性能更差，这 maltodextrins and starch by the system tungstate-hydrogen
peroxide[J]. Starch-Stärke, 1989, 41(8): 303-309.
说明与氧化度相比，氧化淀粉配体的相对分子质量 [12] Bala-piaske A, Tomasik P. Air oxidation of potato starch over
对于鞣制性能的影响更大。另外，VO 3 组（氧化主 vanadium (V) catalyst[J]. Carbohydrate Polymers, 1999, 38(1):
41-45.
要发生于 C-6 位）和 Cu-Fe 组（氧化发生于 C-2、 [13] Harmon R E, Gupta S K, Johnson J. Air-oxidation of starch using
quinquevalent vanadium as catalyst[J]. Starch-Stärke, 1971, 23(4):
C-3 和 C-6 位）的鞣制效果相差不大，这表明淀粉 125-128.
的氧化位点对鞣制性能的影响可能不大。由锆鞣革 [14] Zeng W C, Zhang Z, Gao H, et al. Characterization of antioxidant
polysaccharides from auricularia auricular using microwave-assisted
增厚率（表 4）可知，配体相对分子质量越大，对 extraction[J]. Carbohydrate Polymers, 2012, 89(2): 694-700.
[15] Chen Zhanguang (陈占光), Chen Wuyong (陈武勇). Research and
锆鞣革的填充增厚作用越强 [23] 。考虑到 WO 4 组氧化 preparation of chrome tanning agent for cutting down pickling and its
properties[J]. China Leather (中国皮革), 2001, 30(23): 6-10.
淀粉用于鞣制时性能较差，但其对革的增厚效果显 [16] Zhang Jinwei (张金伟), Wu Jiacheng (吴佳城), Fu Meimei (付美
梅), et al. Application of pickling-free chrome tanning agent in post
著，因此可以考虑将其用于制革复鞣填充工序。
tanning process[J]. Leather Science and Engineering (皮革科学与工
程), 2014, 24(5): 5-9.
3 结论 [17] Wu C, Zhang W H, Liao X P, et al. Transposition of chrome tanning
in leather making[J]. Journal of the American Leather Chemists
Association, 2014, 109(6): 176-183.
在钨酸盐、偏钒酸盐和铜-铁盐等不同催化剂作 [18] Zhang S D, Zhang Y R, Wang X L, et al. High carbonyl content
oxidized starch prepared by hydrogen peroxide and its thermoplastic
用下，双氧水氧化淀粉的结构及作为锆盐配体的鞣 application[J]. Starch-Stärke, 2009, 61(11): 646-655.
[19] Sheng Y, Wang Q H, Xu X C, et al. Oxidation of cornstarch using
制性能差异显著。所得氧化淀粉的氧化度越高，相 oxygen as oxidant without catalyst[J]. LWT-Food Science and
对分子质量越小，锆配合物的鞣制性能越好。铜- Technology, 2011, 44(1): 139-144.
[20] Guo J J, Lian X J, Kang H Q, et al. Effects of glutenin in wheat
铁盐催化所得氧化淀粉的氧化度最高（72.5%），相 gluten on retrogradation of wheat starch[J]. European Food Research
and Technology, 2016, 242(9): 1485-1494.
对分子质量最小（14628），其与锆盐形成的配合物 [21] Chong W T, Uthumporn U, Karim A A, et al. The influence of
ultrasound on the degree of oxidation of hypochlorite-oxidized corn
在皮革中的分布均匀度为 97.8%，皮革收缩温度为 starch[J]. LWT-Food Science and Technology, 2013, 50(2): 439-443.
89.7 ℃，鞣制性能最优，偏钒酸盐次之，钨酸盐最 [22] Thire R M S M, Simao R A, Andrade C T. High resolution imaging
of the microstructure of maize starch films[J]. Carbohydrate
差。氧化淀粉配体的相对分子质量对鞣制性能的影 Polymers, 2003, 54(2): 149-158.
[23] Du Xiaosheng (杜晓声), Shan Zhihua (单志华), Zhou Yanchao (周
响比氧化度更大，值得进一步研究调控和优化其分 燕超 ), et al. Circulative combination tannage and the filling
method[J]. Leather Science and Engineering (皮革科学与工程),
子尺寸。 2013, 23(6): 26-29.