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第 35 卷第 8 期 精 细 化 工 Vol.35, No.8
201 8 年 8 月 FINE CHEMICALS Aug. 2018

催化与分离提纯技术
Pt/SAPO-11-mp 催化棕榈油制航空煤油

一步加氢的响应面优化

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李兴勇 ，陈玉保 ，张少朋 ，张 旭 ，Souliyathai Dona ，杜君臣
（1. 云南师范大学 能源与环境科学学院，云南 昆明 650500；
2. 昆明贵金属研究所，云南 昆明 650106）
摘要：以棕榈油为原料，Pt/SAPO-11-mp 为催化剂，在高压微型固定床反应器中一步加氢制生物航空煤油。在
单因素实验的基础上，利用 Box-Behnken 中心组合实验设计响应面法考察了温度、压力、空速、氢油比（氢气
与棕榈油体积的比，下同）对 C 8 ~C 16 烃的选择性影响。得到最优反应条件为：温度 382.2 ℃，压力 3.9 MPa，空
–1
速 1.2 h ，氢油比 911.0。结合实际，在最优条件下重复 3 次验证实验，C 8 ~C 16 烃的选择性为 44.9%，C 8 ~C 16 异
构烷烃的选择性为 27.9%。
关键词：生物航空煤油；棕榈油；单因素实验；响应面法
中图分类号：S216 文献标识码：A 文章编号：1003-5214 (2018) 08-1346-09

Optimization of Aviation Kerosene on One-Step Hydrotreatment of
Catalytic Palm Oil over Pt/SAPO-11-mp by

Response Surface Methodology

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LI Xing-yong , CHEN Yu-bao , ZHANG Shao-peng , ZHANG Xu , Souliyathai Dona , DU Jun-chen
（1. School of Energy and Environmental Science, Yunnan Normal University, Kunming 650500, Yunnan, China; 2. Kunming
Institute of Precious Metals, Kunming 650106, Yunnan, China）
Abstract: Biological aviation kerosene was produced by one-step hydrotreatment over Pt/SAPO-11-mp
with palm oil as raw material in a high-pressure micro fixed bed. Based on single factor experiments,
Box-Behnken central composite design of response surface methodology was applied to study the effects of
temperature, pressure, space velocity and hydrogen oil ratio (hydrogen volume/palm oil volume, the same
below) on the selectivity of C 8~C 16 hydrocarbons. The experimental results showed that the optimized
reaction conditions were obtained as follows: temperature of 382.2 ℃, pressure of 3.9 MPa, space velocity
–1
of 1.2 h , hydrogen oil ratio of 911.0. Under these conditions, the verification experiment was carried out 3
times, and the selectivities of C 8~C 16 hydrocarbons and C 8~C 16 isoalkanes were 44.9% and 27.9%,
respectively.
Key words: biological aviation kerosene; palm oil; single factor experiment; response surface methodology
Foundation items: National Natural Science Foundation of China (21266032); International S&T
Cooperation Program of China (2015DFA60120); Program for Foreign Experts and Intelligence
Recruitment of Yunnan Provincial Administration of Foreign Experts Affairs (YNS2018005)

[1]
随着经济的快速发展和化石能源的过度消耗， 燃料已成为航空运输业的迫切需求 。目前，国际
导致了环境的严重污染，寻求清洁、可再生的航空 上相继开展了生物质能源的相关研究。生物质是地

收稿日期：2017-09-12; 定用日期：2018-01-08; DOI: 10.13550/j.jxhg.20170738
基金项目：国家自然科学基金项目（21266032）；国家国际科技合作专项（2015DFA60120）；云南省外国专家局引进外国人才和智力
项目计划（YNS2018005）
作者简介：李兴勇（1994—），男，硕士生。联系人：陈玉保（1978—）男，副教授、博士，硕士研究生导师，E-mail：c20072007@163.com。