Page 117 - 201906
P. 117

第 6 期                    苏   炜,等: Fe-多级孔 Hβ 的制备及催化合成二苯甲烷性能                              ·1123·


            中心数量减少,从而降低催化活性。这也与 BET 表                              catalytic properties for benzylation of benzene by benzyl chloride[J].
                                                                   Chinese Journal of Catalysis (催化学报), 2003, 24(8): 579-584.
            征结果相一致。而二苯甲烷的选择性增大是因为介                             [3]   Kun Y L, Zhang C, Li X L, et al. Iron-containing MIL-101 (Cr) as
                                                                   highly active and stable heterogeneous catalysts for the benzylation
            孔的产生,提高了二苯甲烷的扩散性能,降低了深                                 of a romatics with benzyl chloride[J]. Reaction Kinetics Mechanisms
                                                                   & Catalysis, 2016, 120(1): 1-13.
            度苄基化的发生。                                           [4]   Ji Min (纪敏), Wu Haiwei (吴海鸣), He Min (贺民), et al. Kinetic
                                                                   study  on  catalytic  synthesis  of  diphenylmethane  by  immobilized
            2.4    催化剂重复使用性测试                                      AlCl 3[J]. Journal of Dalian University of Technology (大连理工大
                 Fe-Hβ-B 0.10 催化苯-氯化苄反应重复使用性结                      学学报), 2008, 48(2): 168-172.
                                                               [5]   Arafat A, Alhamed Y. Catalytic activity of mesoporous catalysts in
            果见图 9。                                                 Friedel-Crafts  benzylation  of  benzene[J].  Journal  of  Porous
                                                                   Materials, 2009, 16(5): 565-572.

                                                               [6]   Chuabe  V  D.  Benzylation  of  benzene  to  diphenylmethane  using
                                                                   zeolite catalysts[J]. Catalysis Communications, 2004, 5(6): 321-326.
                                                               [7]   Liu Hui (刘惠), Zhang Shuang (张爽), Xie Sujuan (谢素娟), et al.
                                                                   Synthesis characterization and catalytic performance of hierarchical
                                                                   ZSM-11  zeolite  synthesized  via  dual-template  route[J].  Chinese
                                                                   Journal of Catalysis (催化学报), 2018, 39(1): 167-180.
                                                               [8]   Liu Dongmei (刘冬梅), Jiang Hanbo (蒋涵博), Qu Shengtao (曲圣
                                                                   涛 ),  et al.  Study  on  the  alkylation  of  thiophene  and  catalyst
                                                                   deactivation  and  regeneration  with  modified  HZSM-5  zeolite[J].
                                                                   Journal  of  Fuel  Chemistry  and  Technology  (燃料化学学报),  2018,
                                                                   46(3): 355-364.
                                                               [9]   Liu Wanrong (刘万荣), Liu Xinmei (刘欣梅), Xin Ying (辛颖), et al.
                                                                   Preparation of hierarchical Y/ZrO 2 composite[J]. Acta Petrolei Sinica
                                                                   (Petroleum Processing Section) (石油学报:  石油加工), 2018, 34(4):
                                                                   689-695.
                                                               [10]  Tarach  K,  Gora-marek  K,  Tekla  J,  et al.  Catalytic  cracking
                                                                   performance of acid sites properties and their accessibility[J]. Journal

                图 9  Fe-Hβ-B 0.10 催化苯-氯化苄反应重复使用性                   of Catalysis, 2014, 312(2): 46-57.
                                                               [11]  Guo Yongle (郭永乐), Zhang Yu (张钰), Zhao Zhongkui (赵忠奎), et
            Fig.  9    Reusability  of  benzene-benzyl  chloride  reaction   al.  Ceria-modified  hierarchical  Hβ  zeolite  as  a  robust  solid  acid
                    catalyzed by Fe-Hβ-B 0.10                      catalyst  for  alkenylation  of  p-xylene  with  phenylacetylene[J].
                                                                   Chinese Journal of Catalysis (催化学报), 2018, 39(1): 181-189.
                 由图 9 可知,催化剂使用次数增加后,氯化苄                        [12]  Bi Y, Lei X, Xu G, et al. Catalytic fast pyrolysis of kraft lignin over
                                                                   hierarchical  HZSM-5  and  Hβ  zeolites[J].  Catalysts,  2018,  8(2):
                                                                   82-95.
            的转化率略有降低,二苯甲烷的选择性有所提升。                             [13]  Zhang Kongyuan (张孔远), Zhao Xingtao (赵兴涛), Shi Shijie (史世
            这可能是因为随着反应次数的增加,催化剂的活性                                 杰),  et al.  Hydroisomerization  of  n-hexane  over  Pt/Hβ-HZSM-5
                                                                   catalyst[J]. Acta Petrolei Sinica (Petroleum Processing Section) (石
            组分流失,催化剂活性降低,从而降低了反应物的                                 油学报:  石油加工), 2017, 33(2): 204-209.
                                                               [14]  Khan  A,  Chen  P,  Boolchand  P,  et al.  Modified  nano-crystalline
            转化率。活性组分的流失在一定程度上降低了二苯                                 ferrites for high-temperature WGS membrane reactor applications[J].
                                                                   Journal of Catalysis, 2008, 253(1): 91-104.
            甲烷深度苄基化的发生,从而选择性有所增加。重                             [15]  Yang  Jing  (杨静),  Ming  Yang  (明阳), Sun Yu  (孙宇),  et al.
                                                                   Preparation  and  adsorption  desulfurization  performance  of
            复使用 3 次后催化剂依然保持较高的催化能力。说                               Cu-β/SBA-15  composite  molecular  sieves[J].  Acta  Petrolei  Sinica
            明催化剂具有优良的稳定性。                                          (Petroleum Processing Section) (石油学报:  石油加工), 2017, 33(5):
                                                                   919-926.
                                                               [16]  Liu J, Cui L, Wang L, et al. Alkaline-acid treated mordenite and beta
            3    结论                                                zeolites  featuring  mesoporous  dimensional  uniformity[J].  Materials
                                                                   Letters, 2014, 132(10): 78-81.
                                                               [17]  Li Yuping (李宇萍), Wang Tiejun (王铁军), Ma Longlong (马隆龙),
                (1)采用碱处理制备了多级孔 Hβ,采用浸渍法                            et al. Hβ modified Co/SiO 2 catalysts for Fischer-Tropsch synthesis of
                                                                   jet fuel-range hydrocarbons[J]. Journal of Inorganic Materials (无机
            制备了 Fe-多级孔 Hβ,并对其进行了表征,结果表                             材料学报), 2014, 29(6): 599-604.
                                                               [18]  Zeng Maorong (曾茂荣), Luo Gang (罗刚), Wang Yu (王宇), et al.
            明,Hβ 经过碱处理脱除骨架硅形成介孔,Fe 的负                              Quaternary  ammonium  surfactant  assisted  synthesis  of  hierarchical
                                                                   porous  Hβ  zeolite  for  aniline  catalytic  condensation[J].  Journal  of
            载没有破坏多级孔 Hβ 的结构。                                       Chemical Engineering of Chinese Universities (高校化学工程学报),
                                                                   2017, 31(5): 1113-1119.
                (2)在反应温度 75 ℃、反应时间 20 min、苯                    [19]  He Jiajie (何嘉杰), Zhu Baokun (朱保昆), Wu Jiacan (吴家灿), et al.
                                                                   Effect  of  surface  modification  by  H 2  reduction  on  geranylacetone
            与氯化苄物质的量比为 6∶1、催化剂用量为氯化苄                               adsorption and desorption of modified Hβ zeotiles[J]. Ion Exchange
                                                                   and Adsorption (离子交换与吸附), 2017, 33(5): 463-471.
            质量的 2%的条件下,Fe-多级孔 Hβ 的苯-氯化苄烷                       [20]  Guo Haiwei (郭海纬), Fei Zhaoyan (费兆阳), Wang Yu (王宇), et al.
            基化性能为:氯化苄转化率 99.7%,二苯甲烷选择                              Effect of alkali treatment on the catalytic performance of Hβ zeolites
                                                                   in condensation of aniline to diphenylamine[J]. Acta Petrolei Sinica
            性 81.2%。                                               (Petroleum Processing Section) (石油学报:  石油加工), 2017, 33(1):
                                                                   100-107.
                (3)Fe-多级孔 Hβ 分子筛是一种良好的催化合                      [21]  Yang C, Xu Q H. States of aluminum in zeolite β and influence of
                                                                   acidic or basic medium [J]. Zeolites, 1997, 19(5): 404-410.
            成二苯甲烷的催化剂,具有较高的催化活性和较好                             [22]  Wang Junfeng (王俊丰), Shen Jian (沈健), Shi Weiwei (石薇薇), et
                                                                   al.  Experimental  study  on  the  catalytic  alkylation  of  phenol  with
            的稳定性,有着广阔的应用前景。                                        methanol  by  Ce/USY  modified  molecular  sieve[J].  Acta  Petrolei
                                                                   Sinica (Petroleum Processing Section) (石油学报:  石油加工), 2017,
            参考文献:                                                  33(4): 757-762.
                                                               [23]  Xiang  Shouhe  (项寿鹤),  Wang  Jingzhong  (王敬中), Gao Feng  (高
            [1]   Zhan Jinyou (詹金友), Zhang Yaobing (张耀兵), Shen Jian (沈健),   峰),  et al.  Study  on  L  acid  on  Hβ  zeolite[J].  Chinese  Journal  of
                 et al.  Synthesis  of  diphenylmethane  on  Sb-SBA-15[J].  Chemical   Catalysis (催化学报), 1991, 12(5): 404-408.
                 Industry  and  Engineering  Progress  ( 化工进展 ),  2016,  35(5):   [24]  Yang Juhong (杨菊红), Han Xiaoxiang (韩晓祥), Chen Qing (陈青),
                 1460-1465.                                        et al.  Synthesis  of  diphenylmethane  by  alkylation  of  benzene  with
            [2]   Zhou Chunhui (周春晖), Luo Xiping (罗锡平), Ge Zhonghua (葛忠  benzyl chloride by ionic liquid[J]. Fine Chemicals (精细化工), 2010,
                 华),  et al.  Preparation  of  acid-treated  clay-supported  ZnCl 2  and  its   27(6): 610-613.
   112   113   114   115   116   117   118   119   120   121   122