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第 7 期 张璟琳,等: 树苔浸膏中关键气味活性化合物 ·1391·
续表 2
SAFE SPME
①
RI
序 化合物 S1 S2 S1 S2 定性方法 ②
号
HP- TG- HP- TG- HP- TG- HP- TG- HP- TG-
5MS WAX 5MS WAX 5MS WAX 5MS WAX 5MS WAX
醛类
49 糠醛 1466 – – – – – – – + RI, MS, S
50 3-羟基丁醛 1086 – + – – – – – – RI, MS
51 氯化苔黑醛 1490 – + – + – – – – – RI, MS
52 苔黑醛 1550 – + – + – + – + – RI, MS
酸类
53 乙酸 1478 – + – – – – – – RI,MS,S
54 棕榈酸 1968 – + – – – – – – – RI,MS
醇类
55 2-甲基-2-丁醇 1006 – – + – – – – RI, MS
56 仲丁醇 1019 + – + – – – – RI, MS
57 异松香芹醇 1648 + – + – + – – RI, MS
58 丙二醇 1586 + – – – – – – RI, MS, S
59 (-)-反式-松香芹醇 1142 – – – + – + – RI, MS
60 冰片 1167 + – – – + – + – RI, MS, S
61 4-萜烯醇 1178 1594 + + – – + – – – RI, MS, S
62 α-松油醇 1191 1689 + + + + + + + – RI, MS, S, O
63 顺-9-十四碳烯醇 1764 + – – – – – – RI, MS
64 6,6-二甲基二环[3.1.1]庚-2-烯-2-甲醇 1783 + – – – – – – RI, MS
65 丙烯醛缩二乙醇 1276 + + – – – + – RI, MS
66 甘油 1068 2302 + – + – – – – RI, MS, S
67 反式香苇醇 1220 – – + – – – RI, MS
酮类
68 2-吡咯烷酮 2021 + – – – – – – RI, MS
69 1,3,3-三甲基-二环[2.2.1]庚-2-酮 1091 – – + – – – RI, MS
70 D-樟脑 1148 + – – + – – – RI, MS
71 反式-3-戊酮 1163 – – + – – – RI, MS
72 马苄烯酮 1211 1695 + + – + + + – – RI, MS
73 5-(环己基甲基)-2-吡咯烷酮 1451 + – – – – – – RI, MS
74 三羟苯丙酮 1533 + + – – – – – RI, MS
75 8-环十六烯-1-酮 1971 + – – – – – RI, MS
芳香族
76 甲苯 1044 + – + – – – – RI, MS
77 乙苯 862 1131 + + + + – – – – RI, MS, S
78 对二甲苯 870 1139 + + + – – – – – RI, MS
79 苯乙烯 891 1260 + + + + – – – – RI, MS
80 邻二甲苯 1187 – + – + – – – – RI, MS
81 邻乙基甲苯 963 + + – – – – – RI, MS
82 间乙基甲苯 1228 – + – + – – – – RI, MS
83 1,2,4-三甲基苯 1283 – + – + – – – – RI, MS
84 连三甲苯 993 + + – – – – – RI, MS
85 3,5-二羟基戊苯 1762 + – – – – – – RI, MS
86 2-异丙基-5-甲基茴香醚 1236 – – + – – – RI, MS
87 苯酚 983 2001 + + + + + + + + RI, MS, S, O
88 苔黑酚单甲醚 1321 2878 + + – + – + – RI, MS, S, O
89 苔黑酚 1376 + + + + + + – – RI, MS
90 2-乙氧基-4-甲基苯酚 1402 + – – – – – – RI, MS
91 2,5-二甲基间苯二酚 1420 + + – – – – – RI, MS
92 3-甲氧基-5-丙基苯酚烯 1497 + + – + – + – RI, MS
93 β-榄香烯 1392 – – – – + – RI, MS