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的化合物为丁二酸二乙酯(168.94 μg/g,42.47 μg/g), [7] Joulain D, Tabacchi R. Lichen extracts as raw materials in perfumery.
己酸乙酯( 71.72 μg/g , 37.82 μg/g ) ,γ- 丁内 酯 part 1: oakmoss[J]. Flavour & Fragrance Journal, 2009, 24(2): 49-61.
( 38.41 μg/g , 47.00 μg/g ), DL- 苹 果酸二乙酯 [8] Qin Taifeng (秦太峰), Zhou Tiesheng (周铁生). Development and
utilization of yunnan characteristic fragrance resources[M]. Beijing:
(55.44 μg/g,11.65 μg/g),赤星衣酸乙酯(50.78 μg/g,
China Agricultural University Press (中国农业科学技术出版社),
20.37 μg/g)。
2011: 218-219.
从表 4 看出,16 种化合物的 OAV>1,3 种化合 [9] Zhu Huaiyuan (朱怀远), ZhuangYadong (庄亚东), Zhang Ying (张
物的 OAV<1,5 种化合物未能计算 OAV。OAV 值最 映), et al. Analysis of chemical constituents in treemoss concrete by
高的为己酸乙酯(8965,4728),其次为 β-苔黑酚 molecular distillation and solid-phase microextraction methods[J].
Flavor Fragrance Cosmetics (香料香精化妆品), 2012, (2): 1-6.
羧酸甲酯(2949,1233),苔黑酚羧酸乙酯(335,
[10] Zhu Huaiyuan (朱怀远), ZhuangYadong (庄亚东), Zhang Ying (张
209),癸酸乙酯(444,165),戊酸乙酯(197,
映), et al. Analysis of chemical constituents in treemoss concrete by
114),庚酸乙酯(107,38)。OAV 的结果与 FD molecular distillation and simultaneous distillation extraction[J].
因子的结果较为一致,但己酸乙酯、癸酸乙酯、戊 Food Science (食品科学), 2012, 33(10): 212-217.
酸乙酯的结果并不一致,原因可能是阈值的来源主 [11] Liu Qiang (刘强), Mao Deshou (冒德寿), Hou Chun (侯春), et al.
要是水中的,而浸膏基质较为复杂,参考阈值与化 Analysis of treemoss concrete and absolute oil and its application in
tobacco flavoring[J]. Tobacco Science & Technology (烟草科技),
合物在样品中的实际阈值有所差异。
2004, (3): 18-21.
[12] Li Zhijian (李志坚), Zhang Hongxia (张红霞), Wang Lisong (王立
3 结论
松), et al. Analytical study on aroma components in edible lichen
ramalina conduplicans vain[J]. Flavor Fragrance Cosmetics (香料香
两种树苔浸膏通过 SAFE 和 SPME 分别结合
精化妆品), 2015, (6): 17-20.
GC-MS 分析共鉴定出 102 种挥发性风味成分,两种
[13] Song Huanlu (宋焕禄). Molecular sensory science[M]. Beijing:
前处理方式(SAFE 和 SPME)各有优势,但 SAFE Science Press (科学出版社), 2014:241-259.
提取出更多的挥发性成分,较 SPME 提取更优。通 [14] Kreissl J, Schieberle P. Characterization of aroma-active compounds
过 GC-O 结合 AEDA 法确定香气活性成分,结果表 in Italian tomatoes with emphasis on new odorants[J]. Journal of
明树苔浸膏中的香气活性物质为 β-苔黑酚羧酸甲 Agricultural & Food Chemistry, 2017, 65(25): 5198-5208.
[15] Zhu J C, Chen F, Wang L Y, et al. Characterization of the key aroma
酯、戊酮酸乙酯、苔黑酚羧酸乙酯、赤星衣酸乙酯、
volatile compounds in cranberry (Vaccinium macrocarpon Ait.) using
壬酸乙酯、庚酸乙酯、苯乙酸乙酯等。同时利用内
gas chromatography-olfactometry (GC-O) and odor activity value
标法定量并计算 OAV 值,OAV 的结果与 AEDA 法 (OAV)[J]. Journal of Agricultural & Food Chemistry, 2016, 64(24):
确定香气活性成分的结果较为一致。 4990-4999.
[16] Zhang Jinglin (张璟琳), Li Juan (李娟), Wang Juan (王娟), et al.
参考文献: Identification of aroma-active compounds from Hangzhou
[1] Wei Jiangchun (魏江春). Chinese medicinal lichen[M]. Beijing: Chrysanthemum moriflium Ramat extract[J]. Fine Chemicals (精细
Science Press (科学出版社), 1982. 化工), 2018, 35(12): 1905-1913.
[2] Temina M, Levitsky D O, Dembitsky V M. Chemical constituents of [17] Stojanović I Ž, Radulović N S, Mitrović T L, et al. Volatile
the epiphytic and lithophilic lichens of the genus collema[J]. Records constituents of selected Parmeliaceae lichens[J]. Journal of the
of Natural Products, 2010, 4(1): 79-86. Serbian Chemical Society, 2011, 76(7): 987-994.
[3] Ranković B, Mišić M, Sukdolak S. Evaluation of antimicrobial activity [18] Ly H D, Vo T N, Duong T H, et al. A new depside and two new
of the lichens Lasalliapustulata, Parmeliasulcata, Umbilicariacrustulosa, diphenyl ether compounds from the lichen Ramalinafarinacea (L.)
and Umbilicariacylindrica[J]. Microbiology, 2008, 76(6): 817-821. Ach[J]. Phytochemistry Letters, 2011, 11: 146-150.
[4] Yıldırım E, Aslan A, Emsen B, et al. Insecticidal effect of [19] Zhao Y P, Wang L, Li J M, et al. Comparison of volatile compounds
usnealongissima (Parmeliaceae) extract against sitophilusgranarius in two brandies using HS-SPME coupled with GC-O, GC-MS and
(Coleoptera: Curculionidae)[J]. International Journal of Agriculture sensory evaluation[J]. South African Journal for Enology &
& Biology, 2012, 14(2): 303-306. Viticulture, 2016, 32(1): 9-20.
[5] Thadhani V M, M Iqbal C, Sajjad A, et al. Antioxidant activity of [20] Zhao M Q, Han F G, Shao H F, et al. Studies on aroma components
some lichen metabolites[J]. Natural Product Research, 2011, 25(19): of aromatic tobacco condensate[J]. Journal of Northwest Sci-Tech
1827-1837. University of Agriculture and Forestry, 2005, 33(6): 23-26.
[6] Joulain D, Tabacchi R. Lichen extracts as raw materials in perfumery. [21] Zrnzević I, Jovanović O, Zlatanović I, et al. Constituents of
part 2: treemoss[J]. Flavour & Fragrance Journal, 2009, 24(3): Ramalina capitata (Ach.)Nyl. extracts[J]. Natural Product Research,
105-116. 2017, 31(7): 857-860.