Page 195 - 精细化工2019年第8期
P. 195

第 8 期                 孙   琳,等: Mn 3 O 4 @SiO 2 核壳磁性复合材料对钼(Ⅵ)的吸附性能                       ·1683·


                                                               [11]  Lou  X  W,  Archer  L  A,  Yang  Z.  Hollow  micro-nanostructures:
                                                                   Synthesis and applications[J]. Adv Mater, 2008, 20(21): 3987-4019.
                                                               [12]  Yu  Changwu  (于常武), Gao Chao  (高超),  Wang  Lin  (王琳).
                                                                   Adsorption performance of molybdenum onto humus[J]. Environmental
                                                                   Engineering (环境工程), 2015, 33(6): 10-14.
                                                               [13]  Yu  Changwu  ( 于常 武 ), Gao Chao  ( 高超 ).  Performance  and
                                                                                                    2
                                                                   mechanism studies of adsorption molybdenum (MoO 4 ) from waste
                                                                   by ulothrix[J]. Environmental Pollution and Prevention (环境污染与
                                                                   防治), 2015, 37(7): 55-60.
                                                               [14]  Jiang Debin (姜德彬), Yu Jing (余静), Cheng Qingfeng (程庆峰), et
                                                                   al. Preparation and characterization of comositite magnetic material
                                                                   Mn-Zn  ferrite/SiO 2[J].  Environmental  Protection  of  Chemical
                                                                   Industry (化工环保), 2015, 35(5): 536-541.
                                                               [15]  Pu Shengyan (蒲生彦), Wang Kexin (王可心), Ma Hui (马慧), et al.
                                                                   Adsorption properties of magnetic chitosan hydrogelmicrospheres to
                                                                   Pb(Ⅱ) from aqueous solutions[J]. China Environmental Science (中

                                                                   国环境科学), 2018, 38(4): 1364-1370.
                    图 8    循环次数对钼(Ⅵ)吸附的影响                      [16]  Li  Jiapeng  (李家朋).  Preparation  and  magnetic  characterization  of
            Fig. 8    Effect of number of cycles on the adsorption of Mo   nanoparticle[J].  Science  &  Technology  Vision  (科技视界),  2013,
                   (Ⅵ)                                             (24): 322-323.
                                                               [17]  Huang Jianhui (黄建辉), Lin Wenting (林文婷), Xie Liyan (谢丽燕).
                                                                   Preparation  and  adsorption  performance  of  porous  spherical  silica[J].
            3    结论                                                Chinese Journal of Material Research (材料学报), 2017, 31(4): 309-313.
                                                               [18]  Yang Y, Liu J, Li X, et al. Organosilane-assisted transformation from
                                                                   core-shell  to  yolk-shell  nanocomposites[J].  Chemistry  of  Materials,
                (1)采用氧化法和正硅酸乙酯水解法制备了                               2011, 23(16): 3676-3684.
                                                               [19]  Zhu Y, Fang Y, Borchardt L, et al. PEGylated hollow mesoporous
            Mn 3 O 4 @SiO 2 复合材料,经 SEM、TEM 和 VSM 表                 silica nanoparticles as potential drug delivery vehicle[J]. Microporous
                                                                   &Mesoporous Materials, 2011, 141(1/2/3): 199-206.
            征表明,该复合材料为核壳磁性纳米材料,具有磁                             [20]  Pourhashem  S,  Vaezi  M  R,  Rashidi  A.  Investigating  the  effect  of
                                                                   SiO 2-graphene  oxide  hybrid  as  inorganic  nanofiller  on  corrosion
            响应迅速的特点。                                               protection  properties  of  epoxy  coatings[J].  Surface  &  Coatings
                (2)Mn 3 O 4 @SiO 2 磁性纳米材料可以快速吸附                    Technology, 2017, 311: 282-294.
                                                               [21]  Hu L X, Deng G H, Lu W C, et al. Peroxymonosulfate activation by
            钼(Ⅵ),初次饱和吸附量为 145.35  mg/g,其吸附                         Mn 3O 4/metal‐organic  framework  for  degradation  of  refractory
                                                                   aqueous  organic  pollutant  rhodamine  B[J].  Chinese  Journal  of
            过程遵循 Langmuir  等温吸附模型,吸附动力学行                           Catalysis, 2017, 38(8): 1360-1372.
            为符合准二级动力学模型;Mn 3 O 4 @SiO 2 复合材料                   [22]  Xu J, Deng Y Q, Zhang X M, et al. Preparation, characterization, and
                                                                   kinetic study of a core–shell Mn 3O 4@SiO 2 nanostructure catalyst for
            使用 10 次后,饱和吸附量为初次饱和吸附量的                                CO oxidation[J]. ACS Catal, 2014, 4(11): 4106-4115.
                                                               [23]  Yan X Y, Zhou Z G, Wang L, et al. Folate conjugated Mn 3O 4@SiO 2
            91.90%,具有良好的吸附性能。                                      nanoparticles  for  targeted  magnetic  resonance  imaging  in  vivo[J].
                                                                   Materials Research Bulletin, 2014, 57(10): 97-102.
                (3)该磁性纳米复合材料富集回收废水中的钼                          [24]  Hu  H,  Dai  A  T,  Sun  J,  et al.  Aptamer-conjugated  Mn 3O 4@SiO 2
                                                                   core–shell  nanoprobes  for  targeted  magnetic  resonance  imaging[J].
            (Ⅵ)以及修复水体中钼(Ⅵ)污染等具有一定的                                 Nanoscale, 2013, 5(21): 10447-10454.
            应用前景。                                              [25]  Lang Ting (郎婷), Xu Dongdong (许东东), Yi Mengyu (易梦雨), et
                                                                   al. Preparation of nanosized Mn 3O 4 in oxidative medium of hydrogen
                                                                   peroxide[J].  Applied  Chemical  Industry  (应用化工),  2013,  43(12):
            参考文献:                                                  2135-2137.
                                                               [26]  Ozkaya  T,  Baykal  A,  Kavas  H,  et al.  A  novel  synthetic  route  to
            [1]   Tu Y J,  Chan T S,  Tu H W,  et al.  Rapid  and  efficient  removal/   Mn 3O 4  nanoparticles  and  their  magnetic  evaluation[J].  Physica  B:
                 recovery of molybdenum onto ZnFe 2O 4 nanoparticles[J]. Chemosphere,   Condens Matter, 2008, 43(19/20): 3760-3764.
                 2016, 148(4): 452-458.                        [27]  Ishii M, Nakahira M, Yamanaka T. Infrared absorption spectra and
            [2]   Ma  Yingying  (马英英),  Zhang  Lei  (张磊).  The  influence  of   caution distributions in (Mn, Fe) 3O 4[J]. Solid State Commun, 1972,
                 molybdenum on xanthine oxidase activity in mice[J]. Feed Review   11(1): 209-212.
                 (饲料博览), 2016, (3): 36-39.                     [28]  Zhao Hengqin (赵恒勤), Ning Yangkun (宁阳坤), Wang Wei (王威),
            [3]   Qian Dongxu (钱冬旭), Zhang Yalei (张亚雷), Zhou Xuefei (周雪  et al.  Experimental  study  on  adsorption  of  molybdenum  by  D314
                 飞), et al. Research progress of molybdenum polluted water treatment   resin[J].  Mining  and  Metallurgical  Engineering  (矿冶工程),  2018,
                 technology[J].  Chemical  Industry  and  Engineering  Progress  (化工进  38(1): 81-87.
                 展), 2016, 35(2): 617-623.                     [29]  Liu  Zhe  (刘哲),  Zhang  Yuefei  (张越非), Chi Ru’an (池汝安).
            [4]   Brion-Roby  R,  Gagnona  J,  Nosratic  S,  et al.  Adsorption  and   Adsorption kinetics and thermodynamics of pueraia isoflavonoids on
                 desorption of molybdenum (Ⅵ) in contaminated water using a chitosan   HPD-100  macroporous  resin[J].  Journal  of  Wuhan  Institute  of
                 sorbent[J]. Journal of Water Process Engineering, 2018, 23(3): 13-19   Technology (武汉工程大学学报), 2015, 37(4): 17-22.
            [5]   World  Health  Organization.  Molybdenum  in  drinking-water[M].   [30]  Tessier A, Compbell P. Sequential extraction proeedure for the speciation
                 Geneva in Switzerland: WHO Press, 2011: 10-11.     of partieulate traee metals[J]. Anal Chem, 1979, 51(7): 844-851.
            [6]   Tu Y J, You C F, Chang C K, et al. XANES evidence of molybdenum   [31]  Brion  Roby  R,  Gagnona  A  J,  Nostratic  S,  et al.  Adsorption  and
                 adsorption onto novel fabricated nano-magnetic CuFe 2O 4[J]. Chemical   desorption  of  molybdenum  (Ⅵ)  in  contaminated  water  using  a
                 Engineering Journal, 2014, 244(10): 343-349.      chitosan sorbent[J]. Journal of Water Process Engineering, 2018, 23:
            [7]   ChenYuan (陈远). Study on water pollution of lower reaches in zunyi   13-19.
                 Mo-Ni  mine  and  its  biotoxicity[J].  Technological  Innovation  and   [32]  Saptiama I, Kaneti Y V, Suzuki, et al. Template-free fabrication of
                 Application (科技创新与应用), 2012,(23): 121-122.        mesoporous alumina nanospheres using post-synthesis water-ethanol
            [8]   Guo  Zhijun  (郭志军),  Wang  Yanqiu  (王艳秋).  Status  and  counter   treatment  of  monodispersed  aluminium  glycerate  nanospheres  for
                 measures of Mo pollution in Wujintang reservoir[J]. Environmental   molybdenum adsorption[J]. Small, 2018, 14(21): 1800474.
                 Science Guide (环境科学导刊), 2007, 26(4): 59-60    [33]  Tu  Y  J,  Chan  T  S,  Tu  H  W,  et al.  Rapid  and  efficient  removal/
            [9]   Zhang Jie (张捷), Wang Xiaoqin (王小琴), Cao Huabin (曹华斌), et   recovery of molybdenum onto ZnFe 2O 4 nanoparticles[J]. Chemosphere,
                 al.  Effects  of  Mo  pollution  on  livestock  and  poultry  production  in   2016, 148(4): 452-458.
                 southern  Jiangxi[J].  Jiangxi  Journal  of  Animal  Husbandry  and   [34]  Fumihiko O,Takehiro N,Naohito K. Adsorption capability of virgin
                 Veterinary (江西畜牧兽医杂志), 2010, (5): 8-12.           and calcined wheat bran for molybdenum present in aqueous solution
            [10]  Hamed  M  M,  Rizk  H  E,  Ahmed  I  M.  Adsorption  behavior  of   and elucidating the adsorption mechanism by adsorption isotherms,
                 zirconium and molybdenum from nitric acid medium using low-cost   kinetics,  and  regeneration[J].  Journal  of  Environmental  Chemical
                 adsorbent[J]. Journal of Molecular Liquids, 2018, 249(1): 361-370.     Engineering, 2018, 6(4): 4459-4466.
   190   191   192   193   194   195   196   197   198   199   200