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·858·                             精细化工   FINE CHEMICALS                                 第 38 卷

            2.8    力学性能分析                                      酯乳液压敏胶的性能指标为:乳液固含量 62%,黏
                 MMA 用量对高固含量丙烯酸酯乳液压敏胶的                         度 155 mPa·s,环形初粘力(9.53±0.389) N/25 mm,
            环形初粘力、180°剥离强度以及持粘力的影响见表 5。                        180°剥离强度(10.08±0.056) N/25 mm,持粘力超过
                                                               72 h。
                   表 5  MMA 用量对乳液力学性能的影响
            Table 5    Effect of MMA dosage on the mechanical properties   参考文献:
                    of emulsions
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                      MMA    环形初粘力      180°剥离强度                   Preparation of high solid content emulsion type PSA for protective
               样品                                  持粘力/h
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               S1       0     12.5±0.353  9.17±0.283  >72      [2]   DENG R (邓锐). Study on  preparation and  properties of  high-
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               S2      10     9.53±0.389  10.08±0.056  >72
                                                                   大学), 2011.
               S3      20     6.95±0.318  9.07±0.042  >72      [3]   AI Z Q (艾照全), ZHOU Q L (周奇龙), SUN G L (孙桂林), et al.
               S4      30     1.67±0.799  5.96±0.516  >72          Preparation and property study of  high-solid-content  and low-
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            40%,压敏胶的环形初粘力从(12.5±0.353) N/25 mm                     CN104371607B[P]. 2016-08-17.
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            急剧下降至(0.23±0.071) N/25 mm;当 MMA 用量超
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            过 30%时,压敏胶几乎失去压敏性。主要是由于加                               miniemulsion polymerization [J]. Fine Chemicals (精细化工), 2016,
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            增加到 40%时,剥离强度从(10.08±0.056) N/25 mm 急                  with high solid content[J]. Journal of Applied  Polymer Science,
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            时,剥离强度最高。一方面,压敏胶剥离强度随着                                 MBI and  β-CEA and curing agent SAC-100 in acrylate emulsion
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            着凝胶含量的降低而增大            [27] 。当 MMA 用量较少时,              University (南京林业大学), 2015.
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            对剥离强度的影响较大,T g 的增加降低了压敏胶的
                                                                   Preparation and characterization of particle controlled poly(n-butyl
            剥离强度。由表 5 可知,所有样品乳液的内聚强度                               acrylate)/poly(methyl methacrylate) core-shell  emulsion[J].  China
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            液的黏度,提高乳液压敏胶的 T g 以及热稳定性。随                             viscosity and its use in sealants[J]. Chinese Polymer Bulletin (高分
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            触角由 116°减小到 82°,凝胶含量从 62.1%减小到                         composite latexes and latex paints based on these silylated polymer
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            (0.23±0.071) N/25 mm , 180° 剥离强度从 (9.17±           [15]  LIU J (刘捷), CAO C L (曹春雷),  GAO T Z (高天正),  et al.
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