Page 112 - 《精细化工》2021年第5期

·966· 精细化工 FINE CHEMICALS 第 38 卷

表 4 喷墨印花织物青色色块的色牢度和织物断裂强力 [2] El-HENNAWI H, SHAHIN A, REKABY M, et al. Ink jet printing of
Table 4 Color fastness of cyan blocks on inkjet printing fabrics bio-treated linen, polyester fabrics and their blend[J]. Carbohydrate
and breaking strength of fabrics Polymers, 2015, 118(3): 235-241.
[3] HASAN S, INHWAN K, HENRY S, et al. Inkjet printing of reactive
摩擦牢度/级 耐日晒 断裂强力/N silver ink on textiles[J]. ACS Applied Materials & Interfaces, 2019,
织物 色牢度/ 11(6): 6208-6216.
干摩 湿摩 经向 纬向
级 [4] MORRSON W H, AKIN D E. Chemical composition of components
未处理 4 3~4 5 465±2 364±2 comprising bast tissue in flax[J]. Journal of Agricultural and Food
Chemistry, 2001, 49(5): 2333-2338.
SA 预处理 3 3 5~6 469±2 358±2
[5] FANG K J (房宽峻), LIU Z D (刘尊东), CHEN W (陈伟), et al.
SA+SDS 预处理 3 3 5 470±2 374±2 Effect of fabric surface treatment on ink jet printing with reactive dyes[J].
Journal of Textile Research (纺织学报), 2015, 36(2): 128-132, 147.
由表 4 可以看出，未处理亚麻织物喷墨印花青 [6] HAN S (韩双), FANG K J (房宽峻), LIU X M (刘秀明), et al.
Effect of tencel fabric surface modification on the shape and color
色色块的干、湿摩擦色牢度分别为 4 和 3~4 级，预 performance of ink droplet spread[J]. Textile Dyeing and Finishing
处理后印花织物的摩擦色牢度有所降低，织物表面 Journal (染整技术), 2019, 41(1): 27-30.
[7] ZHAO W L (赵伟林), WANG L P (王丽萍), GAO J Y (高建云), et
颜色深度的增加是摩擦色牢度降低的主要原因。而 al. Study of short steaming process of wool fabric for ink-jet printing
经过 SA 和 SA+SDS 处理剂处理后印花亚麻织物青 with formulated surfactant[J]. Knitting Industries (针织工业), 2017,
8(5): 42-44.
色色块的耐日晒色牢度没有明显变化，未处理印花
[8] YANG X J (杨西江). Influence of the non-ionic surfactants on the
亚麻织物的耐日晒色牢度为 5 级，SA 和 SA+SDS property of synthetic thickeners for reactive dye printing[J]. Textile
Auxiliaries (印染助剂), 2005, 22(10): 27-29.
预处理织物分别为 5~6 和 5 级。
[9] XUE X T (薛旭婷), YU H W (于宏伟), JIA L H (贾丽华), et al.
织物的断裂强力包括经纬向的断裂强力，由表 Influences of Gemini cationic surfactants on the dye ability of
4 可以看出，未处理喷墨印花亚麻织物的经纬向断 linen[J]. Textile Auxiliaries (印染助剂), 2006, 23(10): 34-36.
[10] LI H (李红), ZHENG L J (郑来久). Investigation on modification of
裂强力分别为(465±2)和(364±2) N，而 SA+SDS 预处 linen with cationic surfactant[J]. Textile Auxiliaries (印染助剂),
理后经纬向断裂强力略有增加，分别为(470±2)和 2002, 19(5): 19-20.
[11] HUAITIAN B, ANNA-LENA K, KENNETH K, et al. Effects of
(374±2) N。这是由于织物在经过水洗后，附着在织 surfactant and temperature on rheological and structural properties of
物表面的聚合物并没有完全被清洗干净，有少量的 semi dilute aqueous solutions of unmodified and hydrophobically
modified alginate[J]. Langmuir: The ACS Journal of Surfaces and
预处理剂仍吸附在纤维间的空隙及纤维表面，从而 Colloids, 2005, 21(24): 166-174.
对于织物的断裂强力可能会产生一定的影响。 [12] YANG J S, ZHAO J Y, FANG Y. Calorimetric studies of the
interaction between sodium alginate and sodium dodecyl sulfate in
dilute solutions at different pH values[J]. Carbohydrate Research,
3 结论 2008, 343(4): 719-725.
[13] YANG J S (杨继生), CHEN S B (陈生碧), FANG Y (方云). Effect
（1）在 SA 预处理剂中添加表面活性剂 SDS 后， of surfactants on the shear viscosity of dilute aqueous solutions of
sodium alginate[J]. Acta Physico-Chimica Sinica (物理化学学报),
通过二者之间的协同作用可明显降低亚麻织物表面 2009, 25(4): 752-756.
墨滴的渗化程度，提高喷墨印花色块的颜色深度和 [14] LIU Z D (刘尊东). Polymer modification and ink jet printing of
cotton fabric[D]. Tianjin: Tiangong University (天津工业大学),
鲜艳度，且在 SDS 质量分数为 3%时达到最好的颜 2017.
色效果，此时，与 SA 预处理的亚麻织物相比较，墨 [15] SHU D W, FANG K J, LIU X M, et al. Cleaner pad-steam dyeing
technology for cotton fabrics with excellent utilization of reactive
滴的铺展面积减小了 14%，青色和黑色印花色块的 K/S dye[J]. Journal of Cleaner Production, 2019, 241(20): 118371-118378.
值分别提高了 2.6 和 2.1。印花织物的摩擦色牢度略 [16] ZHANG L M (张黎明), GAO S M (高淑敏), WANG J M (王建明).
Research on ink-jet printing process and color management of silk
有下降，耐日晒色牢度和织物的断裂强力无明显改变。 fabric[J]. Wool Textile Journal (毛纺科技), 2017, 45(12): 39-43.
（2）经 SDS 与 SA 预处理后，亚麻织物表面形 [17] ZHANG X Q, FANG K J, ZHANG J F, et al. A vacuum-dehydration
aided pad-steam process for improving reactive dyeing of cotton
成了新的锯齿状膜结构，增加了织物表面的亲水性， fabric[J]. Journal of Cleaner Production, 2017, 168(1): 1193-1200.
改变了织物表面的化学组成，堵塞了纤维间的孔隙，从 [18] RAMANI M, ZHANG L S (张龙生). Development of thickener
instead of sodium alginate in reactive printing[J]. Textile Auxiliaries
而抑制了墨滴的渗化，使得更多的活性染料在滴落 (印染助剂),1993, 10(2): 37-39.
的位置与纤维发生共价结合，提高了喷墨印花效果。 [19] WANG H, KONG H, ZHENG J, et al. Systematically exploring
molecular aggregation and its impact on surface tension and viscosity
（3）本研究为表面活性剂在亚麻织物喷墨印花 in high concentration solutions[J]. Molecules, 2020, 25(7): 1588-1597.
预处理工业中的应用提供了理论参考。下一步的研 [20] SHU R (舒蕊), LI C (李淳), XIA Z M (夏志明). Grafting process of
plasma treated linen fabric[J]. Dyeing & Finishing (印染), 2005,
究重点在于，通过对预处理剂及处理工艺的改进达
31(19): 8-10.
到提高喷墨印花亚麻织物摩擦色牢度的目的。 [21] LIU L H ( 刘立 华 ). Experiment study on flame retardant of
magnesium hydroxide modified by sodium dodecyl sulfate[J].
参考文献: Chemical Technology Market (化工科技市场), 2009, 32(12): 17-20.
[22] AN F, FANG K J, LIU X M, et al. Protease and sodium alginate
[1] MA B J (马冰洁), XING F L (邢凤兰), WANG M L (王墨林). combined treatment of wool fabric for enhancing inkjet printing
Development of JAP scouring aid for linen fabric[J]. Fine Chemicals performance of reactive dyes[J]. International Journal of Biological
(精细化工), 1994, 11(2): 10-14. Macromolecules, 2020, 146: 959-964.