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·342·                             精细化工   FINE CHEMICALS                                 第 40 卷

            以不同的溶解方式、不同结晶温度以及简单的乳化                                 40411-40423.
                                                               [5]   ENDO M, MUKAWA T, SATO N, et al.    Coexistence effect of UVA
            剂对防晒剂结晶速率的影响机理,发现:                                     absorbers to increase their solubility and stability of supersaturation[J].
                (1)在所选 7 种油脂中,DHHB 在 226 中的溶                       International Journal of Cosmetic Science, 2014, 36(6): 546-552.
                                                               [6]   HERZOG B, SCHÄFER A, QUASS K, et al. Synergistic effects of
            解度最大,在低温条件下晶体析出速率也最慢,即共                                binary oil mixtures on the solubility of sunscreen UV absorbers[J].
            轭效应越大的结构对 DHHB 晶体析出抑制作用越大。                             European Journal of Pharmaceutical Sciences, 2020, 145(24): 1-15.
                                                               [7]   HERRERA M L, HARTEL R W. Effect of processing conditions on
                (2)对比未添加乳化剂的样品(DHHB+CC),                           crystallization kinetics of a milk fat model system[J]. Journal of the
            添加乳化剂 Span20、Span80 的样品中 28 d 后 DHHB                   American Oil Chemists' Society, 2000, 77(11): 1197-1205.
                                                               [8]   KUMAR V R, ANDREW J O. Solvent effects on ultrafast photochemical
            溶解度下降率明显减缓,通过偏光显微镜观察,加                                 pathways[J]. Accounts of Chemical Research, 2021, 54(23): 4383-4394.
            入乳化剂后晶核数目明显减少,以及晶体聚集现象                             [9]   MCCLEMENTS D J. Crystals and crystallization in oil-in-water
                                                                   emulsions: Implications for emulsion-based delivery systems[J].
            明显减弱。                                                  Advances in Colloid and Interface Science, 2012, 174: 1-30.
                 本文揭示了溶解方式、储存温度以及乳化剂抑                          [10]  QIU T Q (丘泰球), LI Y H (李月花), CHEN S G (陈树功), et al.
                                                                   Effect of sound field on crystallization nucleation of sucrose
            制 DHHB 防晒剂结晶的机理,为实际产品的制备提                              solution[J]. Technical Acoustics (声学技术), 1993, (1): 15-20.
            供了理论依据,研究结果对开发高防晒指数防晒产                             [11]  DU C H (杜春华), ZHENG S L (郑诗礼), XU H B (徐红彬), et al.
                                                                   Research progress  of solution crystallization enhanced by physical
            品具有重要的科学意义,同时也可以为解决其他活                                 field[J]. Modern  Chemical Industry (现代化工), 2006, 26(S1):
            性成分在化妆品中的应用提供借鉴价值。                                     88-91.
                                                               [12]  HERHOLD A B, ERTAŞ D, LEVINE A J, et al. Impurity mediated
            参考文献:                                                  nucleation in hexadecane-in-water emulsions[J]. Physical Review E,
                                                                   1999, 59(6): 6946-6955.
            [1]   SOHN M, PROST-DAME M, BAYRAKTAR M, et al. Crystallization   [13]  DIMO K, ANTONIA B. Dependence of the critical undercooling for
                 velocity and UV performance of formulations with oversaturated   crystallization on the cooling rate[J]. The Journal of Physical Chemistry
                 UV-filter content[J]. Journal of Pharmaceutical Sciences, 2019,   B, 2010, 114(16): 6946-6955.
                 108(5): 1800-1807.                            [14]  MARTINS P M, FERREIRA A, POLANCO S, et al.   Unsteady-state
            [2]   GROSICK T L, TANNER P. Efficacy as used, not as tested, is true   transfer of impurities during crystal growth of sucrose in sugarcane
                 measure of sunscreen performance 11 disclosure not available at   solutions[J]. Journal of Crystal Growth, 2009, 311(15): 3841-3848.
                 press time[J]. Journal of  the American Academy of Dermatology,   [15]  BROUWERS J, BREWSTER M E, AUGUSTIJNS P. Supersaturating
                 2003, 50(3): 31.                                  drug delivery systems:  The answer to solubility-limited oral
            [3]   HE H L, LI A Q, LI S Q, et al. Natural components in sunscreens:   bioavailability?[J]. Journal of Pharmaceutical Sciences, 2009, 98(8):
                 Topical formulations with sun protection factor (SPF)[J]. Biomedicine   2549-2572.
                 & Pharmacotherapy, 2021, 134: 111-161.        [16]  DALLAS B W, HASSAN B, COLIN W P, et al. Using polymeric
            [4]   SOUZA I D D, BERKOWITZ E, CHEA J D,  et al.  Efficient UV   precipitation inhibitors to improve the absorption of poorly water-
                 filter solubilizers prevent recrystallization favoring accurate and safe   soluble drugs: A mechanistic basis  for utility[J]. Journal of Drug
                 sun protection[J]. ACS Applied Materials & Interfaces, 2018, 10(47):     Targeting, 2010, 18(10): 704-731.





            (上接第 321 页)                                            macrocyclic Schiff base complexes: Influence of procatalyst structure
                                                                   on the ring opening polymerisation of  ε-caprolactone[J]. Chemical
            [20]  COOPER E N, AVERKIEV B, DAY  V  W,  et al. Ring-opening
                 polymerization of ε-caprolactone utilizing aluminum alkyl complexes   Communications, 2008, (39): 4717-4719.
                 bearing dianionic scorpionate ligands[J]. Organometallics, 2021,   [27]  LI Z,  CONSER  K R, JACOBSON E  N.  Asymmetric alkene
                 40(18): 3185-3200.                                aziridination with readily available chiral diimine-based catalysts[J].
            [21]  SHI T,  ZHENG Q  D,  ZUO W W,  et al. Bimetallic  aluminum   Journal  of the American Chemical Society, 1993, 115(12):  5326-
                 complexes supported by bis (salicylaldimine) ligand:  Synthesis,   5327.
                 characterization and ring-opening polymerization of  lactide[J].   [28]  GAO A H, YAO W, XIAO Y, et al. Dinuclear zinc complexes with
                 Chinese Journal of Polymer Science, 2018, 36(2): 149-156.   chiral tetra-azane ligands: Synthesis, structures and catalytic properties for
            [22]  OUYANG H, YUAN D, NIE K, et al. Synthesis and characterization   ring-opening  polymerization of cyclic  esters[J]. Polyhedron, 2015,
                 of dinuclear salan rare-earth metal complexes and their application in   85: 537-542
                 the homo-and copolymerization of cyclic esters[J]. Inorganic   [29]  ZHANG Y Y, YAO W,  LI  H,  et al. Rare-earth-metal  complexes
                 Chemistry, 2018, 57(15): 9028-9038.               supported by new chiral tetra-azane chelating ligands: Synthesis,
            [23]  RÖSCH A, SEIFERT F, VASS V,  et al. Synthesis,  structure, and   characterization, and catalytic properties  for  intramolecular asymmetric
                 catalytic  activity of dinuclear aluminium bis(amidinate) and   hydroamination[J]. Organometallics, 2012, 31(13): 4670-4679.
                 bis(guanidinate) complexes[J]. New Journal of Chemistry, 2021,   [30]  SHELDRICK G M. Crystal structure refinement with SHELXL[J].
                 45(2): 972-981.                                   Acta Crystallographica Section C: Structural Chemistry, 2015, 71(1):
            [24]  WILLIAMS C K, BROOKS N R, HILLMYER M  A,  et al.   3-8.
                 Metalloenzyme inspired  dizinc catalyst for the polymerization of   [31]  YAO W, MU Y, GAO A H, et al. Efficient ring-opening polymerization
                 lactide[J]. Chemical Communications, 2002, (18): 2132-2133.   of  ɛ-caprolactone  using anilido-imine-aluminum  complexes in the
            [25]  BREYFOGLE  L E, WILLIAMS C K, YOUNG JR V G,  et al.   presence of benzyl alcohol[J]. Polymer, 2008, 49(10): 2486-2491.
                 Comparison of structurally analogous Zn 2, Co 2, and Mg 2 catalysts for   [32]  YU X F, WANG Z X. Dinuclear aluminum complexes supported by
                 the polymerization of cyclic esters[J]. Dalton Transactions, 2006, (7):   amino-or imino-phenolate ligands: Synthesis, structures, and ring-opening
                 928-936.                                          polymerization catalysis of rac-lactide[J]. Dalton Transactions, 2013,
            [26]  ARBAOUI A, REDSHAW C, HUGHES D L. Multinuclear alkylaluminium   42(11): 3860-3868.
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