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·2350· 精细化工 FINE CHEMICALS 第 36 卷

缩聚法是主要方法。当前催化剂以有机钛和有机锡 comparison of thermal behavior and solid state structure with its
terephthalate and naphthalate homologues[J]. Polymer, 2015, 62:
为主，酶和有机碱是催化剂的研究热点。2,5-呋喃二
28-38.
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二甲酸基聚酯接近，2,5-呋喃二甲酸聚酯对 CO 2 、 796-804.
O 2 和 H 2 O 的阻隔性优于对苯二甲酸基聚酯，但 2,5- [14] Ma J P, Yu X F, Xu J, et al. Synthesis and crystallinity of poly
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呋喃二甲酸聚酯的断裂伸长率较低，不利于后续加 [15] Terzopoulou Z, Tsanaktsis V, Nerantzaki M, et al. Decomposition
工和应用。为改善 2,5-呋喃二甲酸聚酯的力学和热 mechanism of polyesters based on 2,5-furandicarboxylic acid and
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学等性能，采取了无机纳米改性、扩链改性和共聚 Polymer Degradation and Stability, 2016, 132: 127-136.
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取得较好的综合改性效果。柔性适中的共聚单体是 64-67.
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2,5-呋喃二甲酸聚酯共聚改性成功的关键。可以预
synthesize high-molecular-weight biobased polyesters from 2,5-
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酯达到绿色可持续的目标。 polyesters from 2,5-furandicarboxylic acid and long-chain aliphatic
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