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第 7 期                   李贾东,等:  小粒径 Fe 3 O 4 磁粉的制备及其在有机合成中应用                            ·1427·


                           表 4    催化反应时间                           1181.
                      Table 4    Time of catalytic reaction    [3]   Wan Guangqin (万光琴). The preparation of iron oxide red from iron
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             Alfa-Fe 3O 4   2.5   3.0      2.5      3.0
                                                                   89-98..
             自制 Fe 3O 4   0.5     0.5      0.5      0.5        [5]   Wang  Xingyao  (王兴尧),  Lv  Feifei  (吕飞飞). Synthesis of  Fe 3O 4
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                 2,3-二苯基喹喔啉(Ⅶ)         [11] :浅黄色固体,熔               (天津大学学报), 2018, 24: 45-50.
                               1
            点 130~131  ℃。 HNMR  (400 Hz,  CDCl 3 ),  δ:        [6]   He K,  Xu C Y,  Zhen L,  et al.  Hydrothermal  synthesis  and
            8.18~8.24 (m, 2H), 7.78~8.83 (m, 2H), 7.52~7.57 (m,    characterization  of  single-crystalline  Fe 3O 4,  nanowires  with  high
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            4H), 7.29~7.33 (m, 6H);。HRMS, m/Z: [M+H]   理论          aspect  ratio  and  uniformity[J].  Materials  Letters,  2007,  61(14/15):
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                        1
            105~106 ℃。 HNMR (400 Hz, CDCl 3 ), δ: 7.96~7.99    [8]   Zou Tao (邹涛), Guo Canxiong (郭灿雄), Duan Xue (段雪), et al.
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            6H,  2CH 3 )。HRMS,  m/Z:  [M+H]   理论值 159.0878,        strong  magnetism[J].  Fine  Chemicals  (精细化工),  2002,  19(12):
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            实际值 159.0844。                                      [9]   Ma Cong (马聪). Study on preparation of Fe 3O 4 magnetic powder for
                 甲基-2,3-二苯基喹喔啉(Ⅸ)          [11] :浅棕色固体,            developer by waste steel pickling[D]. Tianjin: Tianjin University (天
                            1
            熔点 116~117 ℃。HNMR (400 Hz, CDCl 3 ), δ: 8.09 (d,       津大学), 2013.
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            J=8.5, 1.5 Hz, 1H, Ar—H), 7.50~7.56 (m, 4H, Ar—H),     magnetic  powder  from  spent  pickling  liquors[D].  Tianjin:  Tianjin
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            7.32~7.39 (m, 6H, Ar—H), 2.64(s, 3H, CH 3)。HRMS,   [11]  Hong Y L, Shu H Y, Jia D, et al. Magnetic Fe 3O 4 nanoparticles as
                      +
            m/Z: [M+H]   理论值 297.1347,  实际值 297.1347。              new, efficient, and reusable catalysts for the synthesis of quinoxalines
                 2, 3, 6-三甲基喹喔啉(Ⅹ)        [11] :棕色固体,熔             in water[J]. Aust J Chem, 2010, 63: 1290- 1296.
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                          1
            点 90~91 ℃。 HNMR(400  Hz,  CDCl 3 ),  δ:  7.86(d,       oxide as an efficient catalyst for the one-pot, solvent-free synthesis of
            J=8.5 Hz, 1H, Ar—H), 7.75 (s, 1H, Ar—H), 7.47 (d,      α-aminonitriles[J]. Tetrahedron Letters, 2009, 50(20): 2322-2325.
            J=8.5 Hz, 1H, Ar—H), 2.70 (s, 6H, 2CH 3 ), 2.56 (s, 3H,   [13]  Chen Yajie (陈亚杰), Lin Shangxin (林赏心), Pu Jixiong (蒲继雄).
                                    +
            CH 3 )。HRMS, m/Z: [M+H]   理论值 173.1034,  实际            Preparation  and  catalytic  performance  of  Fe 3O 4  nanoparticles[J].
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            值 173.1007。
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                                              2+
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            氧化为 Fe ,使其达到 n(Fe )∶n(Fe )=1.8∶1.0,                    197416032.
            利用 pH 计数值作为氧化过程中监测铁比例的手段。                          [16]  Yang  Xiyun  (杨喜云),  Gong  Zhuqing  (龚竹青),  Peng  Changhong
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            Fe 3 O 4 磁粉,将其应用于香豆素衍生物和喹喔啉衍生                          2008, 39(3): 454-458.
                                                                                                            2+
                                                                                                     3+
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