Page 181 - 《精细化工》2020年第1期
P. 181
第 1 期 贾济如,等: 氨基蒽醌聚氨酯紫色微球的粒径调控及形貌 ·167·
球外壳,采用界面聚合法,制备了自着色的聚氨酯 [5] Zhang Yanyan (张妍妍), Yin Yunjie (殷允杰), Wang Chaoxia (王潮
紫色微球。 霞). Preparation and properties of photochromic microcapsule via
emulsification-chemical crosslinking method[J]. Fine Chemicals (精
(2)考察了微球制备过程中一些因素对微球粒 细化工), 2018, 35(10): 1636-1640.
径大小与分布的影响。与 OP-10、Tween80 和 Span80 [6] Fan Fei (范菲), Wang Chaoxia (王潮霞). Study on preparation and
相比,SDBS 更适合作为聚氨酯微球的乳化剂,当它 particle size of polyurethane-photochromic microcapsules[J]. Journal
of Functional Materilas (功能材料), 2013, 44 (10): 1511-1514.
用量为质量分数 3.5%时,微球的平均粒径为 350 nm, [7] Zhao X, Meng Q, Liu J, et al. Hydrophobic dye/polymer composite
分布较窄。随着乳化速度的增加,微球乳液的平均粒 colorants synthesized by miniemulsion solvent evaporation
径明显减小,当乳化速度为 8000 r/min 时,微球粒 technique[J]. Dyes & Pigments,2014, 100(1): 41-49.
[8] Fang K, Zhang L, Cai Y, et al. Hollow disperse dyes/copolymer
径分布最为均匀。发色体用量为 1.0 mmol 时,微球
composite nanospheres[J]. Dyes & Pigments,2017, (136): 191-196.
的 PDI 最小。 [9] Fang K, Ren B. A facile method for preparing colored nanospheres of
(3)通过微观形貌观察,氨基蒽醌聚氨酯微球 poly (styrene-co-acrylic acid)[J]. Dyes & Pigments, 2014, 100(1):
50-56.
颗粒圆整,表面光滑,且内部呈空心结构。对棉织
[10] Liu Yongzheng (刘永政), Sui Xiaofeng (隋晓锋), Mao Zhiping (毛
物进行印花处理,微球可大量覆盖在棉纤维表面和 志平), et al. Preparation of disperse dye microcapsules based on
间隙中,且可保持较为完整的形貌。氨基蒽醌聚氨 pickering emulsion stabilized by cellulose nanocrystals [J]. Dyeing
and Finishing (印染), 2017, (3): 4-8.
酯紫色微球印花织物比聚氨酯包覆染料微胶囊印花
[11] Song Ci (宋词), Tong Shengzhi (童盛智), Lv Yong (吕勇), et al.
织物颜色性能优异,且具较高色牢度。 Colorimetric properties of reversible thermo chromic UV ink [J].
本文制备的自着色氨基蒽醌聚氨酯微球,也可 Packaging Engineering (包装工程), 2017, 38(1): 76-80.
[12] Liao Peipei (廖培培). Application of the embedding and dyeing
作为一种高分子染料来对织物染色。微球不溶于水,
process of oil-soluble natural pigment[D]. Suzhou: Soochow University
染色后残液中的微球可直接过滤提取回收,为绿色 (苏州大学), 2012.
环保染色提供了可行性。 [13] Standardization Administration of the People's Republic of China (中
国国家标准化管理委员会). Textiles-Tests for color fastness-Color
参考文献: fastness to washing with soap or soap and soda: GB/T
3921—2008[S]. Beijing:Standards Press of China (中国标准出版
[1] Rambabu K, Bharath G, Monash P, et al. Effective treatment of dye
polluted wastewater using nanoporous CaCl 2 modified polyethersulfone 社), 2008: 1-4.
membrane[J]. Process Safety and Environmental Protection, 2019, [14] Standardization Administration of the People's Republic of China(中
国国家标准化管理委员会). Textiles-Tests for color fastness-Color
124(4): 266-278.
fastness to rubbing: GB/T 3921—2008[S]. Beijing:Standards Press of
[2] Lafi R, Gzara L, Lajimi R H, et al. Treatment of textile wastewater
China (中国标准出版社), 2008: 1-3.
by a hybrid ultrafiltration/electrodialysis process[J]. Chemical
Engineering and Processing-Process Intensification, 2018, 132(10): [15] Mao Haiyan (冒海燕), Wang Chaoxia (王潮霞), Fang Guiquan (方
105-113. 桂全), et al. Preparation and particle size analysis of phthalocyanine
[3] Kurtan U, Amir M, Baykal A. Fe 3O 4@ Nico-Ag magnetically recyclable green pigment microcapsule coated by polyamide [J]. New Chemical
nanocatalyst for azo dyes reduction [J]. Applied Surface Science, Materials (化工新型材料), 2011, 39(10): 70-72.
2016, 363(2): 66-73. [16] Wang Fan (王凡), Wu Xiaoqing (吴晓青), Sun Qian (孙谦), et al.
[4] Fan F, Zhang W, Wang C. Covalent bonding and photochromic Synthesis and properties of self-colored waterborne polyurethane
properties of double-shell polyurethane-chitosan microcapsules fabric dye[J]. Polyurethane Industry (聚氨酯工业), 2018, 33(1):
crosslinked onto cotton fabric[J]. Cellulose. 2015, 22 (2): 1427-1438. 12-15.
(上接第 121 页) battery electrode[J]. Advanced Materials, 2017, 29(33): 1701828.
[20] Kwak H W, Eom J, Cho S Y, et al. High-toughness natural polymer
[15] Ma Yan (马艳), Li Zhi (李智), Dai Fangyin (代方银), et al. A review nonwoven preforms inspired by silkworm cocoon structure[J].
on modification of silk and silk fabrics[J]. Science of Sericulture (蚕 International Journal of Biological Macromolecules, 2019, 127:
业科学), 2016, 42(6): 1106-1112. 146-152.
[16] Koh L D, Cheng Y, Teng C P, et al. Structures, mechanical properties [21] Zhang J, Kaur J, Rajkhowa R, et al. Mechanical properties and
and applications of silk fibroin materials[J]. Progress in Polymer structure of silkworm cocoons: A comparative study of Bombyx
Science, 2015, 46: 86-110. mori, Antheraea assamensis, Antheraea pernyi and Antheraea mylitta
[17] Tao H, Amsden J J, Strikwerda A C, et al. Metamaterial silk silkworm cocoons[J]. Materials Science and Engineering: C, 2013,
composites at terahertz frequencies[J]. Advanced Materials, 2010, 33(6): 3206-3213.
22(32): 3527-3531. [22] Ramesh S, Liew C W. Dielectric and FTIR studies on blending
[18] Pereira R F P, Brito-Pereira R, Gonçalves R, et al. Silk fibroin of[xPMMA-(1−x) PVC] with LiTFSI[J]. Measurement, 2013, 46(5):
separators: A step toward lithium-ion batteries with enhanced 1650-1656.
sustainability[J]. ACS Applied Materials & Interfaces, 2018, 10(6): [23] Zhao Y, Wu C, Peng G, et al. A new solid polymer electrolyte
5385-5394. incorporating Li 10GeP 2S 12 into a polyethylene oxide matrix for
[19] Tang Y, Deng J, Li W, et al. Water-soluble sericin protein enabling all-solid-state lithium batteries[J]. Journal of Power Sources, 2016,
stable solid-electrolyte interphase for fast charging high voltage 301: 47-53.