Page 37 - 精细化工2020年第2期
P. 37

第 2 期                          程春晖,等:甲醇制烃类反应机理研究进展                                       ·239·


            关键问题仍然相当模糊。                                            of dimethyl ether to hydrocarbons on zeolite H-ZSM-5: The reaction
                 MTH 工艺的基础研究为催化剂的开发提供了                             mechanism for formation of primary  olefins[C]Proceedings of the
                                                                   Fifth International Conference on Zeolites,1980.
            有力支持。尽管已经提出了可靠的反应网络,但仍                             [15]  Munson E J, Kheir A A, Lazo N D, et al. In situ solid-state NMR
            然有许多理论上的问题亟待解决,今后 MTH 反应                               study of methanol-to-gasoline chemistry in zeolite HZSM-5[J]. The
                                                                   Journal of Physical Chemistry, 1992, 96(19): 7740-7746.
            机理的研究需要重点关注以下几个方面:(1)初始
                                                               [16]  Lesthaeghe D, Van Speybroeck V, Marin G B, et al. The rise and fall
            C—C 键形成的反应路径;(2)不同反应路径之间                               of direct mechanisms in methanol-to-olefin catalysis: An overview of
            的确切关系;(3)调控不同反应路径,以增加产品                                theoretical contributions[J]. Industrial & Engineering  Chemistry
                                                                   Research, 2007, 46(26): 8832-8838.
            的选择性,并减少积碳的生成;(4)利用分子动力                            [17]  Olsbye U, Svelle S, Lillerud K P,  et al. The formation and
            学(MD)模拟不同沸石骨架结构和复杂分子环境中                                degradation  of active species during methanol conversion  over
                                                                   protonated zeotype catalysts[J]. Chemical Society  Reviews, 2015,
            发生的化学反应。这些贡献有助于理解在 MTH 反
                                                                   44(20): 7155-7176.
            应中分子筛催化剂的构效关系,为催化剂的开发和                             [18]  Wang W, Hunger M. Reactivity of surface alkoxy species on acidic
            催化性能的优化奠定基础。                                           zeolite catalysts[J]. Acc Chem Res, 2008, 39(48): 895-904.
                                                               [19]  Sinclair P E, Catlow C R A. Generation of carbenes during methanol
            参考文献:                                                  conversion over brönsted acidic aluminosilicates. A computational
                                                                   study[J]. The Journal of Physical Chemistry B, 1997, 101(3): 295-298.
            [1]   Sun X, Mueller S, Shi H, et al. On the impact of co-feeding aromatics   [20]  Michael S. Methanol-to-hydrocarbons: Catalytic materials and their
                 and olefins for the methanol-to-olefins reaction on HZSM-5[J]. Journal   behavior[J]. Microporous & Mesoporous Materials, 1999, 29(1/2):
                 of catalysis, 2014, 314: 21-31.                   3-48.
            [2]   Hemelsoet K, Mynsbrugge J V D, Wispelaere K D, et al. Unraveling   [21]  Qian Zhen (钱震), Zhao Wenping (赵文平), Geng Yuxia (耿玉侠),
                 the reaction mechanisms governing methanol-to-olefins catalysis by   et al. Advance in research on the mechanism of methanol conversion
                 theory and experiment[J]. ChemPhysChem, 2013, 14(8): 1526-1545.   to hydrocarbons [J]. Journal of Molecular Catalysis(China) (分子催
            [3]   Olsbye U, Svelle S, Bjørgen M,  et al. Conversion of methanol to   化), 2015,29(6):593-600.
                 hydrocarbons: How zeolite cavity and pore size controls product   [22]  Lesthaeghe D, Van Der Mynsbrugge J, Vandichel M,  et al. Full
                 selectivity[J]. Cheminform, 2012, 51(24): 5810-5831.     theoretical cycle for both ethene and propene formation during
            [4]   Wu X, Xu S, Wei Y, et al. Evolution of C—C bond formation in the   methanol-to-olefin conversion in H-ZSM-5 [J]. ChemCatChem,
                 methanol-to-olefins process: from direct coupling to autocatalysis[J].   2011, 3(1): 208-212.
                 ACS Catalysis, 2018, 8(8): 7356-7361.         [23]  Lesthaeghe D, Van Speybroeck V, Marin G B, et al. Understanding
            [5]   Yu Xianbo (虞贤波), Liu Ye (刘烨), Yang Yongrong (阳永荣), et
                                                                   the failure of direct C-C coupling in the zeolite-catalyzed methanol-
                 al. Mechanisms of methanol-to-olefin reaction  [J]. Progress In
                                                                   to-olefin process [J]. Angewandte Chemie, 2010, 45(11): 1714-1719.
                 Chemistry (化学进展), 2009, 21(9): 1757-1762.
                                                               [24]  Liu Y, Müller S, Berger D, et al. Formation mechanism of the first
            [6]   Xu S, Zhi Y, Han J, et al. Advances in catalysis for methanol-to-olefins
                                                                   carbon-carbon bond and the first olefin in the methanol conversion
                 conversion[M] Advances in Catalysis. Academic Press, 2017, 61:
                                                                   into hydrocarbons[J]. Angewandte Chemie International Edition,
                 37-122.
                                                                   2016, 55(19): 5723-5726.
            [7]   Lesthaeghe D, Van Speybroeck V, Marin G B, et al. Understanding
                 the failure of direct C—C coupling in the zeolite-catalyzed methanol-   [25]  Van Speybroeck V, Van der Mynsbrugge J, Vandichel M, et al. First
                 to-olefin process[J]. Angewandte Chemie International Edition, 2006,   principle kinetic studies of zeolite-catalyzed methylation reactions[J].
                 45(11): 1714-1719.                                Journal of the American Chemical Society, 2010, 133(4): 888-899.
            [8]   Michael Stöcker. Methanol-to-hydrocarbons: Catalytic materials and   [26]  Lesthaeghe D, Van Speybroeck V, Marin G B, et al. What role do
                 their  behavior[J]. Microporous and  Mesoporous Materials, 1999,   oxonium ions and oxonium ylides play in the ZSM-5 catalysed
                 29(1/2):3-48.                                     methanol- to-olefin process?[J]. Chemical Physics Letters, 2006, 417(4):
            [9]   Jiang Y, Wang W, Marthala V R R, et al. Effect of organic impurities   309-315.
                 on the hydrocarbon formation  via the decomposition of surface   [27]  Song W, Marcus D M, Hui F, et al. An oft-studied reaction that may
                 methoxy groups on acidic zeolite catalysts[J]. Journal of Catalysis,   never have been:  Direct catalytic  conversion of methanol  or
                 2006, 238(1): 21-27.                              dimethyl ether to  hydrocarbons on the solid acids HZSM-5  or
            [10]  Dahl I M, Kolboe S. On the Reaction Mechanism for hydrocarbon   HSAPO-34[J]. Journal of the American Chemical Society, 2002,
                 formation from methanol over SAPO-34: i. Isotopic labeling studies   124(15): 3844-3845.
                 of the co-reaction  of ethene and methanol[J]. Journal of  Catalysis,   [28]  Wu X, Xu S, Zhang W,  et al. Direct  mechanism of the first
                 1994, 149(2): 458-464.                            carbon-carbon bond formation in the  methanol-to-hydrocarbons
                                                                   process[J]. Angewandte Chemie International Edition, 2017, 56(31):
            [11]  Munson E J, Lazo N D, Moellenhoff M E, et al. Carbon monoxide is
                                                                   9039-9043.
                 neither an intermediate nor a catalyst in MTG chemistry on zeolite
                 HZSM-5[J]. Journal of the American Chemical Society, 1991,   [29]  Shen Wenjie (申文杰). The direct  mechanism for the formation of
                 113(7): 2783-2784.                                the first C—C bond in the methanol to hydrocarbon reaction [J].
            [12]  Grimsrud E P, Kebarle P. Gas phase ion equilibriums studies of the   Wuli Huaxue Xuebao (物理化学学报), 2017, 33(11): 19-20.
                 hydrogen ion  by methanol, dimethyl ether, and water. Effect of   [30]  Wang Youhe (王有和), Wu Chengcheng (吴成成), Liu Zhongwen
                 hydrogen bonding[J]. Journal of  the American Chemical Society,   (刘忠文),  et al. Progresses in reaction processes,mechanism and
                 1973, 95(24): 7939-7943.                          kinetics of methanol to olefins [J]. Industrial Catalysis (工业催化),
            [13]  Hellring S D, Schmitt K D, Chang C D. Synthesis and decomposition   2018, 26(1): 13-21.
                 of trimethyloxonium ZSM-5, a purported intermediate in  methanol   [31]  Teketel S, Olsbye U, Lillerud K P, et al. Selectivity control through
                 conversion into gasoline[J].  Journal  of the Chemical Society  Chemical   fundamental  mechanistic insight  in  the conversion of methanol  to
                 Communications, 1987, 17(17): 1320-1322.          hydrocarbons over zeolites[J]. Microporous & Mesoporous Materials,
            [14]  Van Den Berg J P, Wolthuizen J P, Van Hooff J H C. The conversion   2010, 136(1): 33-41.
   32   33   34   35   36   37   38   39   40   41   42