Page 125 - 《精细化工》2021年第8期

第 8 期 薄晓帆，等: 溶胶-凝胶法制介孔 Pd/m-TiO 2 催化连续流 Suzuki 偶联反应 ·1619·

唑双三氟甲磺酰亚胺盐。在连续流工艺中使用 Pd/C 12184-12188.
催化剂时，在 6.8 min 内可获得 89%的反应收率（序 [7] BORKOWSKI T, TRZECIAK A M, BUKOWSKI W, et al.
Palladium(0) nanoparticles formed in situ in the Suzuki-Miyaura
号 6），而自制 0.7% Pd/m-TiO 2 催化剂在相同时间内 reaction: The effect of a palladium( Ⅱ ) precursor[J]. Applied
可获得 99%的反应收率（序号 8）。 Catalysis A General, 2010, 378(1): 83-89.
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酸的 Suzuki 偶联反应，确定了最优工艺条件： [12] WU L (吴莉), LONG Y (龙雨), MA J T (马建泰), et al. Research
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Improving activity and selectivity with a new family of porous
下反应收率均达到了 99%。此外，0.7% Pd/m-TiO 2
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