Page 151 - 《精细化工》2022年第10期
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第 10 期             陈德君,等: Pt/WO 3 -TiO 2 /ZrO 2 -Al 2 O 3 甘油加氢体系中 Al 2 O 3 的双功能作用       ·2085·


            上存在较小的 Pt 纳米颗粒,对 H 2 的活化能力较好,                          over Li 2B 4O 7-modifified tungsten-zirconium composite oxides
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            Brönsted 酸,在甘油氢解制备 1,3-PDO 的反应中表                   [9]   LEI N, ZHAO  X  C, HOU  B L,  et al. Effective hydrogenolysis of
            现出最优性能。                                                glycerol to 1, 3-propanediol over metal-acid concerted Pt/WO x/Al 2O 3
                                                                   catalysts[J]. ChemCatChem, 2019, 11(16): 3903-3912.
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                (1)以 P123 为模板剂,利用 ZrOCl 2 、磷钨酸、                [11]  DENG C H, LENG L, DUAN X Z, et al. Support effect on the bimetallic
            AlCl 3 、钛酸四丁酯制备了一种 Al 2 O 3 掺杂的四元                      structure of Ir-Re catalysts and their performances in glycerol
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            WO 3 -TiO 2 /ZrO 2 -Al 2 O 3 复合氧化物。                    410: 81-88.
                (2)少量 Al 2 O 3 的引入提高了 ZrO 2 、TiO 2 及           [12]  ARUNDHATHI R, MIZUGAKI T, MITSUDOME T,  et al. Highly
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            及 Pt 纳米团簇,后者在 H 2 中原位产生 Brönsted 酸                     2013, 6: 1345-1347.
            中心,促进 1,3-PDO 的生成。然而,WO 3 及 Pt 团簇                  [13]  CHENG S J, FAN Y Q, ZHANG  X X,  et al. Tungsten-doped
                                                                   siliceous mesocellular foams-supported platinum catalyst for glycerol
            之间的相互作用仍有待深入研究。
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                (3)在保持 Pt、WO 3 -TiO 2 用量均不变的情况下,                   Environmental, 2021, 297: 120428.
            催化剂中不同 ZrO 2 与 Al 2 O 3 质量比表现出一定的协                 [14]  LIANG  Y X, SHI G J, JIN K. Promotion effect of  Al 2O 3  on
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            TiO 2 / ZrO 2 -Al 2 O 3 催化剂具有最佳催化活性,此时甘                2365-2376.
            油的转化率可达 39.0%,1,3-PDO 的选择性则高达                      [15]  ZHU S H, GAO X Q, ZHU Y L, et al. SiO 2 promoted Pt/WO x/ZrO 2
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