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·2256· 精细化工 FINE CHEMICALS 第 40 卷

在反应中全程无需 H 2 S 气瓶，通过稀硫酸与硫 [19] ZHANG X M, XIONG W J, PENG L L, et al. Highly selective
absorption separation of H 2S and CO 2 from CH 4 by novel azolebased
氢化钠原位生成 H 2 S，结合低温的 THF 对 H 2 S 的极
protic ionic liquids[J]. Aiche Journal, 2020, 66: 1547-5905.
大溶解性，通过调节温度改变反应压力，代替了传 [20] JALILI A H, SHOKOUHI M, MAURER G, et al. Measuring and
统 H 2 S 气瓶，密封条件保证反应体系内 H 2 S 气体足 modelling the absorption and volumetric properties of CO 2 and H 2S
in the ionic liquid 1-ethyl-3-methylimidazolium tetrafluoroborate[J].
量且不会泄露。同时，ILs 作为催化剂应用于 β-巯 The Journal of Chemical Thermodynamics,2019, 131: 544-556.
基丙酸的合成反应，可以有效地减少副产物的生成， [21] WANG X, ZENG S J, WANG J L, et al. Selective separation of
hydrogen sulfide with pyridinium-based ionic liquids[J]. Industrial &
提高目标产物的选择性和收率，值得引起广泛关注 Engineering Chemistry Research, 2018, 57(4): 1284-1292.
并继续研究。 [22] XIONG W J, SHI M Z, PENG L, et al. Low viscosity superbase
protic ionic liquids for the highly efficient simultaneous removal of
参考文献： H 2S and CO 2 from CH 4[J]. Separation and Purification Technology,
2021, 263: 118417.
[1] FURLAN B, CASAR Z, STERK D, et al. 3-Mercaptopropionic acid [23] ZHANG X M, XIONG W J, SHI M Z, et al. Task-specific ionic
as a new reagent for the industrially applicable synthesis of highly liquids as absorbents and catalysts for efficient capture and
pure O-desmethylvenlafaxine from venlafaxine[J]. Journal of Sulfur conversion of H 2S into value-added mercaptan acids[J]. Chemical
Chemistry, 2015, 36(1): 67-73. Engineering Journal, 2021, 408: 127866.
[2] LI G (李果), XU G W (许戈文). Preparation and properties of WPU [24] GAO H J, XIE N, ZHANG J X, et al. Synthesis and application of
modified with sulfur-containing chain extender[J]. Fine Chemicals carboxyethylthiosuccinic acid by thiol-ene click reaction: As a novel
(精细化工), 2019, 36(11): 2286-2291. rust remover with corrosion inhibition properties[J]. Journal of
[3] WANG Y H ( 王艳华 ), LI M ( 李猛 ). Development of Chemical Sciences, 2020, 132: 56.
3-mercaptopropionicacid preparation[J]. Chemistry and Adhesion (化 [25] SUN J, WANG X Y, GAO H J, et al. The effect of regional
学与粘合), 2021, 43(4): 297-299. selectivity on the corrosion inhibition properties of synthetic ionic
[4] FURLAN B, CASAR Z, STERK D, et al. 3-Mercaptopropionic acid liquid via the synergistic action of the cation and anion[J]. New
as a new reagent for the industrially applicable synthesis of highly Journal of Chemistry, 2021, 45: 20201-20213.
pure O-desmethylvenlafaxine from venlafaxine[J]. Sulfur Chem, [26] ZHAO Y S, GAO H S, ZHANG X P, et al. Hydrogen sulfide
2015, 36: 67-73. solubility in ionic liquids (ILs): An extensive database and a new
[5] BO X M (薄宪明), HE F X (贺芬霞), ZHANG J (张婧). Method for ELM model mainly established by imidazolium based ILs[J]. Journal
preparing 3-mercaptopropionic acid: CN102229550A[P]. 2011-11-02. of Chemical & Engineering Data, 2016, 61: 3970-3978.
[6] ZHANG S G (张圣光). Study on the synthesis of β-mercaptopropionic [27] HUANG K, CAI D N, CHEN Y L, et al. Dual lewis base
Acid[D]. Zhengzhou: Zhengzhou University (郑州大学), 2016. functionalization of ionic liquids for highly efficient and selective
[7] DONG G J, SOOG R. Method for producing 3-mercaptopropionic capture of H 2S[J]. Chem Plus Chem, 2014, 79(2): 241-249.
acid, and methods using same for producing carboxylic acid ester [28] WANG X, ZENG S J, WANG J L, et al. Selective separation of
compound having mercapo group and thiourethane-based optical hydrogen sulfide with pyridinium-based ionic liquids[J]. Industrial
merterial: US2018179154A[P]. 2018-06-28. and Engineering Chemistry Research, 2018, 57(4): 1284-1292.
[8] AKIRA S, HIDEMASA A. Method for producing β-mercaotocarboxylic [29] CHIAPPE C, POMELLI C S. Hydrogen sulfide and ionic liquids:
acids: US0004017A1[P]. 2011-01-06. Absorption, separation, and oxidation[J]. Topics in Current Chemistry,
[9] ZHOU Y (周英). Synthesis of 3-mercaptopropionic with refining 2017, 375(3): 52.
by-product hydrogen sulfide[D]. Chengdu: Chengdu University of [30] WU S L (伍松玲). Synthesis and structure confirmation of nitrogen-
Technology (成都理工大学), 2013. containing heterocycles derived from alkynyl-weinreb amide with
[10] HUANG J Z (黄军左), ZHOU Y (周英), MA Y G (马玉刚). DBN(DBU)[D]. Hangzhou: Zhejiang University of Technology (浙
Heterogeneous catalytic synthesis of 3-mercaptopropionic acid by 江工业大学), 2017.
homemade magnesium oxide catalyst[J]. Industrial Catalysis (工业催 [31] LEMUS J, SANTIAGO R, HOSPITAL-BENITO D, et al. Process
化), 2015, 23(12): 1017-1021. analysis of ionic liquid-based blends as H 2S absorbents: Search for
[11] GU J R (顾建荣). Preparation method of 3-mercaptopropionic acid: thermodynamic/kinetic synergies[J]. ACS Sustainable Chemistry and
CN101941930B[P]. 2013-06-19. Engineering, 2021, 9(5): 2080-2088.
[12] HAJLME K, HIDETO T, TADASHI S, et al. Michael addition of [32] SHANG Y, LI H P, ZHANG S J, et a1．Guanidinium-based ionic
nitromethane to α,β-unsaturated carbonyl compounds over solid base liquids for sulfur dioxide sorption[J]. Chemical Engineering Journal,
catalysts[J]. Journal of Molecular Catalysis A: Chemical, 2000, 2011, 175: 324-329.
155(1/2): 23-29. [33] YANG Z Z, HE L N, MIAO C, et a1. Lewis basic ionic liquids-
[13] XU J S (徐景士), WANG H M (王红明), CHEN H Z (陈慧宗). catalyzed conversion of carbon dioxide to cyclic carbonates[J].
Study on catalytic Michael addition reaction with solid base[J]. Advanced Synthesis & Catalysis, 2010, 352(13): 2233-2240．
Chemical Research and Application (化学研究与应用), 2003, (6): [34] LIU J (刘菊), SHI L (石磊), CHEN F (陈飞), et al. Thermostable
847-848. strong alkalinity ionic liquid using for synthesis of dimethyl
[14] GU W Z X (古屋政幸), XIAO C D S (小川达矢), XI C X (西村雄). carbonate[J]. Fine Chemicals (精细化工), 2020, 37(7): 1438-1446.
Method for the manufacture of β-mercaptocarboxylic acid: [35] HUANG J Y (黄金艳), YANG W J (杨文娟), JIANG L H (蒋丽红),
CN103946210A[P]. 2014-07-23. et a1. Catalytic synthesis of n-borneol by imidazole ionic liquid[J].
[15] WU Y Q (吴玉强), YI X J (易先君), DING Z W (丁宗旺), et al. Fine Chemicals (精细化工), 2021, 38(5): 1002-1022.
Synthesis of 3-mercaptopropionic acid: CN112608259B [P]. 2022-12-06. [36] WEI L, GENG Z Y, LIU Y T, et al. Highly efficient and reversible
[16] WEILHARD A, QADIR M I, SANS V, et al. Selective CO 2 H 2S capture by mercapto carboxylic anion functionalized ionic
hydrogenation to formic acid with multifunctional ionic liquids[J]. liquids[J]. Journal of Molecular Liquids, Journal of Molecular
ACS Catalysis, 2018, 8(3): 1628-1634. Liquids, 2021, 343: 116975.
[17] YVES L. Process for the manufacture of mercaptocarboxylic acids [37] ZHANG X M (张效敏), SHI M Z (史名珍), XIONG W J (熊文杰),
from unsaturated carboxylic acids: US6689907B1[P]. 2004-02-10. et al. Research progress in the ionic liquid-mediated capture and
[18] HIDEMASA A, AKIO K, AKIRA S. Method for producing conversion of H 2S[J]. Science China Chemistry (中国科学: 化学),
β-mercaotocarboxylic acids: US8258340B2[P]. 2012-09-04. 2020, 50(5): 594-602.