Page 63 - 《精细化工》2023年第11期

第 11 期 罗 竞，等: 基于纤维素基固相萃取材料分析尿液中的苯丙胺毒品 ·2375·

丙胺氨基上的氢原子与 Cell-COOH 羧基中的 C==O preparation approach[J]. Analytical and Bioanalytical Chemistry,
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形成—C==O…H—NH—氢键。 [7] ZHANG J Y (张金颐), CUI Y (崔阳), HE L (何柳), et al.
基于以上研究，Cell-COOH 对苯丙胺的吸附作 Modification of P(NVP-DVB) and its application in the detection of
BPA in aqueous solution[J]. Fine Chemicals (精细化工), 2023,
用主要归因于 Cell-COOH 与苯丙胺之间的静电引力 40(1): 75-86.
和氢键协同作用（图 11f）。当 2.1≤pH≤9.9 时， [8] GUIMARAES L B, TEIXEIRA L, AMORIM F, et al. Solid phase
extraction combined with energy dispersive X-ray fluorescence
Cell-COOH（–）与 AMP（+）之间存在的静电引力 spectrometry for multielement determination[J/OL]. Applied Spectroscopy
大大降低了空间位阻，使得材料与苯丙胺更易形成 Reviews, 2022. DOI:10.1080/05704928.2022.2066687.
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氢键，而氢键的作用会减弱羧基负电荷的稳定性， prospect of solid phase extraction technology[J]. Chinese Journal of
促进羧酸中氢的解离 [41] ，两种作用力相互促进提高 Chemical Engineering, 2022, 42: 245-255.
[10] ASTUTI M P, JASEMIZAD T, PADHYE L P. Surface modification
了 Cell-COOH 对苯丙胺的吸附能力。 of coconut shell activated carbon for efficient solid-phase extraction
of N-nitrosodimethylamine from water[J]. Journal of Separation
Science, 2021, 44(2): 618-627.
3 结论 [11] AL-SAIDI H M, ABDEL-FADEEL M A, EL-SONBATI A Z, et al.
Multi-walled carbon nanotubes as an adsorbent material for the solid
以纤维素为原料，对其进行改性制备纤维素基 phase extraction of bismuth from aqueous media: Kinetic and
thermodynamic studies and analytical applications[J]. Journal of
萃取材料（Cell-COOH），将其作为固相萃取材料 Molecular Liquids, 2016, 216: 693-698.
用于苯丙胺的富集浓缩，并建立固相萃取-高效液相 [12] OYE A R, ARRACHART G, TAVERNIER R, et al. Terephthalaldehyde-
phenolic resins as a solid-phase extraction system for the recovery of
色谱法用于尿液中苯丙胺毒品的分析检测。改性后 rare-earth elements[J]. Polymers (Basel), 2022, 14(2): 311.
纤维素表面变得粗糙并在其表面出现羧基官能团； [13] CHEN J L, TAN L J, CUI Z G, et al. Graphene oxide molecularly
imprinted polymers as novel adsorbents for solid-phase microextraction
Cell-COOH 在苯丙胺的分离富集中表现出良好的富 for selective determination of norfloxacin in the marine environment[J].
Polymers (Basel), 2022, 14(9): 1839.
集能力、特异性、抗干扰能力与重复使用性，在最
[14] WANG F (王芳), LIU M (刘敏), LI X Y (李小燕), et al. Preparation
佳条件下，即 pH 为 8，萃取剂用量为 0.5 g/L，萃取 and properties of clobetasol propionate molecular capture based on
graphene oxide[J]. Fine Chemicals (精细化工), 2019, 36(8): 1525-1531.
时间为 30 min，洗脱剂为 0.8%（体积分数）的 HCl [15] KODALI J, PAVULURI S, ARUNRAJ B, et al. Tapping the potential
水溶液，洗脱剂用量为 0.08 L/g，洗脱时间为 20 min， of a glucosamine polysaccharide-diatomaceous earth hybrid adsorbent in
the solid phase extraction of a persistent organic pollutant and toxic
Cell-COOH 对苯丙胺的萃取回收率可达 98.3%，使 pesticide 4,4′-DDT from water[J]. RSC Advances, 2022, 12(9):
用第 7 次时，萃取回收率仍能保持在 92%以上。 5489-5500.
[16] ZHANG Z Q (张志强), XU S Y (徐淑艳), WANG Q L (王全亮).
Cell-COOH 材料主要通过静电引力和氢键与苯丙胺 Progress in preparation and application of functional cellulose
相互作用，达到富集回收的目的。在实际尿液样品分 microspheres[J]. Fine Chemicals (精细化工), 2022, 39(10): 1953-
1963.
析中，该法表现出较高的灵敏度（LOQ=8.0 μg/L； [17] AHMAD H, ALHARBI W, BINSHARFAN I I, et al. Aminophosphonic
LOD=2.5 μg/L）及较好的重现性（RSD≤4.71%）， acid functionalized cellulose nanofibers for efficient extraction of
trace metal ions[J]. Polymers, 2020, 12(10): 2370.
具有快速、灵敏、重现性高等优点，在检测尿液样 [18] ABUJABER F, JIMENEZ-MORENO M, GUZMAN B F J, et al.
品中苯丙胺类毒品的预处理方面具有良好的应用潜力。 Simultaneous extraction and preconcentration of monomethylmercury
and inorganic mercury using magnetic cellulose nanoparticles[J].
Mikrochimica Acta, 2019, 186(7): 400.
参考文献： [19] MHD H M A C, CHING Y C, ILLIAS H A, et al. Cellulose
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Determination of 89 drugs and other micropollutants in unfiltered
wastewater and freshwater by LC-MS/MS: An alternative sample （下转第 2393 页）