Page 57 - 201807
P. 57

第 7 期                   辛   成,等:  界面聚合网状壳体聚氨酯相变微胶囊的制备与性能                                ·1125·


            量为 3.5 g 时,质量损失最低,致密性最好。                               7-60.
                                                               [6]   Chalco-Sandoval W, Fabra M J, López-Rubio A, et al. Use of phase
                                                                   change materials to develop electrospun coating of interest in food
                                                                   packaging applications[J]. Journal of Food Engineering, 2017, 192:
                                                                   122-128.
                                                               [7]  Li  Qingdan (李庆丹), Zhu Dongmei (朱冬梅), Li Jiaojiao (李娇娇),
                                                                   et al. Preparation and  phase change properties  of  paraffin
                                                                   microcapsules[J]. Fine Chemicals (精细化工), 2011, 28(1): 10-13.
                                                               [8]   Wang H P, Yuan Y C, Rong M Z, et al. Microencapsulation of styrene
                                                                   with melamine-formaldehyde resin [J]. Colloid & Polymer Science,
                                                                   2009, 287(9): 1089-1097.
                                                               [9]   Liu Xing (刘星),  Liu Hongyan (刘红研), Wang Shujun (汪树军).
                                                                   Encapsulation and thermal performance of paraffin shape-stabilized
                                                                   phase change materials[J]. Fine Chemicals (精细化工), 2006, 23(1):
                                                                   8-11.
                                                               [10]  Giro-paloma J, Martinez M, Cabeza  L F,  et al. Types, methods,
                                                                   techniques, and applications for microencapsulated phase  change
                   图 7  TEA 用量对微胶囊热稳定性影响                           materials (MPCM): A review[J]. Renewable & Sustainable Energy
            Fig. 7    Thermal stability of  microcapsules  with different   Reviews, 2016, 53: 1059-1075.
                   dosage of TEA                               [11]  Jamekhorshid A, Sadrameli S  M, Farid M. A review of
                                                                   microencapsulation methods of phase change materials (PCMs) as a
                                                                   thermal energy storage (TES) medium[J]. Renewable & Sustainable
            3   结论                                                 Energy Reviews, 2014, 31(2): 531-542.
                                                               [12]  Lu S F, Shen T W, Xing J W, et al. Preparation and characterization
                                                                   of cross-linked polyurethane shell microencapsulated phase change
                 采用界面聚合法,以 SMAS 为乳化剂、硬脂酸                           materials by interfacial polymerization [J]. Materials  Letters, 2017,
            丁酯为芯材、IPDI 和 TEA 为反应单体,制备了性能                           295(10): 2061-2067.
                                                               [13]  Zhang Yao (张姚), Zhao Di (赵迪), Jiao Xin (焦鑫),  et al.
            优异的具有网状结构的相变微胶囊,其在纺织服装、                                Fabrication and characterization of microcapsulated dementholized
            建筑材料和航空航天等领域具有良好的应用前景。                                 peppermint oil with polyurea shell[J]. Act Polymerrica Sinica (高分
                                                                   子学报), 2016, (1): 46-52.
                 (1)SEM 表明,当芯/壁质量比为 2.73∶1、                    [14]  Guo J B, Zhang J M, Zhang Q, et al. Fabrication of cholesteric liquid
            TEA 用量为 3.5 g 时,所制备微胶囊表面光滑平整,                          crystal microcapsulates by interfacial polymerization and potential as
                                                                   photonic materials[J]. 2013, 3(44): 21620-21627.
            壳体完整致密。                                            [15]  Siddhan  P, Jassal  M,  Agrawal A K.  Core content and  stability  of
                 (2)粒径分布图表明,芯/壁质量比越大,微                             n-octadecane-containing polyurea microencapsules produced by
            胶囊的粒径分布越均一。                                            interfacial polymerization[J]. Journal of Applied Polymer Science,
                                                                   2007, 106(2): 786-792.
                 (3)FTIR 结果显示,所制备的微胶囊壳体为                       [16]  Cho J S, Kwon A, Cho C G. Microencapsulation of octadecane as a
            聚氨酯结构,并有少量异氰酸根残留。                                      phase-change material by interfacial polymerization in an emulsion
                                                                   system[J]. Colloid & Polymer Science, 2002, 280(3): 260-266.
                 (4)DSC 结果表明,所制备微胶囊具有优良                        [17]  Zou G L, Lan X Z, Tan Z C,  et al. Microencapsulation of
            的储热性能,胶囊化后相变行为不受影响。                                    n-hexadecane as a phase change  material in polyurea  [J]. Acta
                                                                   Physico-Chimica Sinica, 2004, 20(1): 90-93.
                 (5)单体 TEA 用量对微胶囊热稳定性和致密                       [18]  Wang Xuan (王轩), Zhu Jinhua (朱金华),  Wang Zixiao (王紫潇).
            性有较大影响,当 TEA 用量为 3.5 g 时,微胶囊的                          Effect of core preparation conditions on the performance of paraffin
                                                                   microcapsules in  polyurea[J]. Polymer Materials Science and
            致密性和热稳定性最好。                                            Engineering (高分子材料科学与工程), 2016, 32(5): 124-129.
                                                               [19]  Zhang H Z,  Wang X D. Synthesis and properties  of
            参考文献:                                                  microencapsulated  n-octadecane with polyuria shells containing
                                                                   different soft segments for heat energy storage and thermal regulation
            [1]   Xu B, Li P W, Cholik C. Application of phase change materials for   [J]. Solar Energy Materials and Solar Cells, 2009, 93(8): 1366-1376.
                 thermal energy storage in concentrated solar thermal power plants: A   [20]  Zhan S P, Chen S H, Chen L, et al. Preparation and characterization
                 review to recent developments[J]. Applied Energy, 2015, 160: 286-   of polyuria microencapsulated phase change material by interfacial
                 307.                                              polycondensation  method[J]. Powder Technology, 2016, 292: 217-
            [2]   Alva G, Lin Y X,  Liu L K,  et al. Synthesis, characterization and   222.
                 applications of microencapsulated phase change materials in thermal   [21]  Wang Junhua (王俊华). Preparation of controlled-release, skin-care
                 energy storage: a review[J]. Energy and Buildings, 2017, 144: 276-   microcapsules and their applications to fabrics [D].  Shanghai:
                 294.                                              Donghua University (东华大学), 2008.
            [3]   Jayalath A, Nicolas R S, Sofi M,  et al. Properties  of cementitious   [22] Duan  Wuhai  (段武海). Microencapsulation of PEG energy-storage
                 mortar and concrete containing micro-encapsulated  phase change   phase change material and analysis of its morphology and properties
                 materials[J]. Construction and Building Materials, 2016, 120: 408-   [D]. Shanghai: Donghua Univresity (东华大学), 2007.
                 417.                                          [23]  Ye Xing (叶星), Chen Yan (陈艳), Chen Dazhu (陈大柱). Synthesis
            [4]   Iqbal K, Sun  D M.  Development of thermos-regulating   and thermal-storing properties of anti-yellowing microencapsulated
                 polypropylene fiber containing microencapsulated phase  change   n-octadecane with polyurea shells[C]// Academic of National
                 materials[J]. Renewable Energy, 2014, 71(11): 473-479.   Polymer Materials Science  and Engineering Conference. Wuhan:
            [5]   Sarier N, Onder E. Organic phase change materials and their textile   Wuhan Institute of Technology Press (武汉工程大学出版社), 2012,
                 application: An overview[J]. Thermochimica    Acta, 2012, 540(14):   991-992.
   52   53   54   55   56   57   58   59   60   61   62