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第 8 期 张闻扬，等: 反式茴脑低温氧气氧化性质及其产物 ·1369·

且反应温度越高，反式茴脑氧化程度越深。由此可 hydrogen peroxide catalyzed by oxovanadium aromatic carboxylate
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见，当反式茴脑在生产、利用或运输贮存时，若长 [9] Li Zhengqiu (李正球), Ha Chengyong (哈成勇), Ma Yijing (马一
时间受热或者接触空气中的氧气时，会发生氧化降 静), et al. Preparation of anisaldehyde from oxidation of anethole by
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低其纯度，带来经济损失。所以为减小氧化反应对 产化学与工业), 2009, 29(4): 59-62.
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synthesized by anisole oxidation with phase transfer catalyze
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[11] Gao Rong (高蓉), Li Wenhong (李稳宏), Li Dong (李冬), et al.
Preparation of anisaldehyde from star anise oil by ozonolysis
3 结论 reaction[J]. Chinese Journal of Food Science (食品科学), 2008,
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其氧化反应可分为 3 个阶段：首先是氧气被缓慢吸 光), et al. Biotransformation of anethole to anisaldehyde in aqueous
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pathway in an Arthrobacter sp[J]. Journal of Biological Chemistry,
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（2）反式茴脑吸收氧气生成过氧化物被碘量法
blockedmutants[J]. Journal of Biotechnology, 2003, 105(1): 61-70.
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过氧化物浓度均先增大后减小，过氧化物的较佳生 民共和国国家卫生和计划生育委员会). peroxide value of food (食
品中过氧化值的测定): GB 5009. 227-2016[S]. Beijing (北京):
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英), et al. Thermal decomposition temperature of organic peroxides
（3）反式茴脑低温氧化产物与反应温度有关，且 studied by CPVT[J]. Chemistry world (化学世界), 1998, 13(10):
541-543.
产物比较复杂，主要有茴香醛、乙醛、茴香环氧化物、
[19] Tang Shengwei (唐盛伟). An investigation on the liquid phase
茴香二醇和茴香偶酰等，反式茴脑的转化率和氧化程 oxidation of toluene by air[D]. Chengdu: Sichuan University, 2005.
度随着温度的升高而变大，当温度为 55 ℃时，茴香醛 [20] He Jie (何洁). The thermal hazards of organic peroxides [D].
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光 ), et al. Optimization of biotransformation conditions for
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