Page 77 - 201906

第 6 期 刘佳慧，等: 功能化石墨烯改性无胺型水性聚氨酯的制备 ·1083·

有核壳结构的无胺型 SiO 2 -NH 2 -GO/WPUA 乳液。拉 松). Adevance in composite latex modified by inorganic nanoparticles[J].
伸测试表明，SiO 2 -NH 2 -GO 对 SiO 2 -NH 2 -GO/WPUA Chinese Journal of Colloid & Polymer (胶体与聚合物), 2006,
24(3): 38-40.
胶膜在力学性能上有增强作用，当 SiO 2 -NH 2 -GO 的 [10] Sun Fang (孙芳), Liu Xiaokang (刘晓康), Jiang Shengling (江盛玲),
添加量在 0.75%时，胶膜具有较好的力学性能。 et al. Study on properties of water-borne polyurethane-acrylate
hybrid emulsion[J]. Adhesionin China (粘接), 2011, (6): 46-50.
（2）热性能测试结果表明，SiO 2 -NH 2 -GO 的加 [11] Fei Guiqiang (费贵强),Wang Jiao (王佼), Wang Haihua (王海花),
入一定程度上提高了 SiO 2 -NH 2 -GO/WPUA 胶膜的 et al. Preparation and properties of waterborne polyurethane
热分解温度，当 SiO 2 -NH 2 -GO 质量分数为 0.75%时， acrylate/graphene oxide anti-corrosion coating[J]. Polymer Materials
Science and Engineering (高分子材料科学与工程), 2016, 32(4):
SiO 2 -NH 2 -GO/WPUA 较 WPUA 胶膜热分解温度提 173-178.
高了 14.51 ℃。 [12] YBB 00152002—2015.Medicinal aluminum foil (药用铝箔)[S].
China Medical Science and Technology Press (中国医药科技出版
（3）合成的 SiO 2 -NH 2 -GO/WPUA 乳液易氧化物
社), 2015.
指标复合医药包装材料标准，在合成复合乳液过程 [13] GB/T 2791—1995.Adhesives,T peel strength test method for a
没有加入挥发性有机溶剂，用氢氧化钠作为中和剂， flexible-to-flexible text specimen assembly (胶粘剂 T 剥离强度试验
方法、挠性材料对挠性材料)[S]. China Standard Press (中国标准出
体系中不使用三乙胺，是一种真正意义上的无毒、 版社), 1995.
零 VOC 的环境友好材料。合成的 SiO 2 -NH 2 -GO/ [14] Peng Cuihua (彭翠华). Study on the interpenetrating polymer
WPUA 胶黏剂适用于医药包装。 networks based on CO-PU/HCAA[D]. Wuhan:Central China Normal
University (华中师范大学), 2008.
[15] Chen Fei ( 陈飞 ). End-group analysis of aqueous polyurethane
参考文献：
dispersions (PUD) and chain extension reaction in prepolymer mixing
[1] Yu Du (喻都), Xiao Haijun (肖海军), Shi Weizhe (石伟哲). The procss[D]. Hefei: Anhui University (安徽大学), 2014.
research progress of medical polyurethane adhesive[J]. Orthopaedic [16] Ren Li (任丽), Wang Lixin (王立新). Interface modification of APS
Biomechanics Materials and Clinical Study (生物骨科材料与临床 on PPy/SiO 2 conducting nanocomposites [J]. Journal of Functional
研究), 2015, 12(3): 63-66. Materials (功能材料), 2004, 35(1): 69-70.
[2] Li Jianjun (李建军). Study on properties of waterborne polyurethane [17] Pang Jiuyin (庞久寅). Preparation, structure and properties of
matting resin modified by epoxy resin[D]. Guangzhou:South China nanometer-silica-acrylate hybrid latexes[D]. Beijing: China Academy
University of Technology (华南理工大学), 2015. of Forestry (中国林业科学研究院), 2006.
[3] Yan Caibin (颜财彬). Synthesis of modified waterborne polyurethane [18] Cho J W, Sun H L. Influence of silica on shape memory effect and
adhesive with modifications and its adhesion to nonpolar films[D]. mechanical properties of polyurethane–silica hybrids[J]. European
Guangzhou:South China University of Technology (华南理工大学), Polymer Journal, 2004, 40(7): 1343-1348.
2013. [19] Liu Ruiqi (刘瑞琪), Pan Hui (潘卉), Wang Shuxia (王淑霞), et al.
[4] Li Jiadong (李佳栋). Study on preparation and anti-corrosion Preparation and application of nano-SiO 2/grapheneoxide nanocomposites[J].
properties of modified-graphene water borne coatings[D]. Jilin: Chemical Research (化学研究), 2018, 29(1): 90-98.
Northeast Electric Power University (东北电力大学), 2017. [20] Mohanty S, Krishnamurti N. Synthesis and characterization of
[5] Yang Jia (杨佳). Preparation, characterization and properties of aqueous cationomeric polyurethanes and their use as adhesives[J].
graphene/polymer nanocomposites[D]. Wuhan:Hubei University (湖 Journal of Applied Polymer Science, 1996, 62(12): 1993-2003.
北大学), 2013. [21] Wang Xuechuan (王学川), Zong Yishan (宗奕珊), Qiang Taotao (强
[6] Li Zhihua (李智华). Study on waterborne polyurethane modified by 涛涛). Synthesis and properties of castor oil-based waterborne
nanomaterials[D]. Hefei:Anhui University (安徽大学), 2010. polyurethane-acrylate hybrid latex using a emulsifier-free method[J].
[7] Wang Lei (王磊), Shen Yiding (沈一丁), Lai Xiaojuan (赖小娟). Journal of Functional Materials (功能材料), 2014, 45(15): 15070-
Preparation and properties of polyurethane/silica hybrid emulsion[J]. 15074.
Polymer Materials Science and Engineering (高分子材料科学与工 [22] Lupu A, Valsesia A, Bretagnol F, et al. Development of a
程), 2011, 27(6):137-141. potentiometric biosensor based on nanostructured surface for lactate
[8] Cheng Limin (程丽敏). Preparation and properties of waterborne determination[J]. Sensors & Actuators B: Chemical, 2007, 127(2):
polyurethane/nanosilicacomposites[D]. Hefei:University of Science 606-612.
and Technology of China (中国科学技术大学), 2011. [23] Yang B Y, Shimokawa W, Kao C L, et al. Emulsion type acrylic
[9] Shao Qian (邵谦), Wang Chengguo (王成国), Ge Shengsong (葛圣 pressure sensitive adhesives: US 20050250887 A1[P]. 2005-11-10.