Page 154 - 《精细化工》2021年第7期

第 38 卷第 7 期 精 细 化 工 Vol.38, No.7
202 1 年 7 月 FINE CHEMICALS July 2021

皮革化学品
缓香型玉米醇溶蛋白微胶囊乳液的制备及应用

徐群娜 1,2,3 ，白忠薛 1,2 ，马建中 1,2 ，杨羽西 1,2 ，李娇娇 1,2

（1. 陕西科技大学 轻工科学与工程学院，陕西 西安 710021；2. 轻化工程国家级实验教学示范中心，
陕西 西安 710021；3. 陕西省轻化工助剂化学与技术协同创新中心，陕西 西安 710021）

摘要：为改善皮革的特殊气味并提升其应用性能，以玉米醇溶蛋白（Zein）、艾叶香精（AAE）以及普兰尼克 F127
等为原料，通过反溶剂法制备缓香型玉米醇溶蛋白微胶囊（AAE@ZMs）乳液，再将 AAE@ZMs 乳液与成膜剂
己内酰胺改性酪素复配后应用于皮革涂饰。结果表明，Zein 与 F127、AAE 和戊二醛通过化学交联和氢键相互作
用，同时 F127 和 AAE 可使 Zein 中的氨基酸重排并发生荧光猝灭。当 Zein 和 AAE 质量分别为 0.1 g 和 0.01 g
时，制得的 AAE@ZMs 乳液中微胶囊平均粒径约为 298.6 nm，且具有较好的分散性和稳定性，AAE@ZMs 对香
精的包覆率和负载率分别可以达到 73.2%和 5.8%，微胶囊中的 AAE 在良溶剂中释放 120 h 后的累积释放率约为
83.1%。将复配后的 AAE@ZMs 乳液应用于皮革涂饰后，涂饰革样中 AAE 的释放周期为 6 周，对金黄色葡萄球
菌和大肠杆菌均具有较好的抑制效果，同时涂饰革样还展现出较好的机械性能。
关键词：玉米醇溶蛋白；艾叶香精；反溶剂法；缓香；微胶囊；皮革化学品
中图分类号：TS5; S513 文献标识码：A 文章编号：1003-5214 (2021) 07-1436-08

Preparation and application of zein microcapsules
emulsion for fragrance release

1,2
1,2
1,2
1,2
XU Qunna 1,2,3 , BAI Zhongxue , MA Jianzhong , YANG Yuxi , LI Jiaojiao
（1. College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science & Technology, Xi'an
710021, Shaanxi, China; 2. National Demonstration Center for Experimental Light Chemistry Engineering Education,
Xi'an 710021, Shaanxi, China; 3. Shaanxi Collaborative Innovation Center of Industrial Auxiliary Chemistry &
Technology, Xi'an 710021, Shaanxi, China）
Abstract: In order to improve the special odor of leather and enhance its application performance, sustained
release zein microcapsule (AAE@ZMs) emulsion was prepared by anti-solvent method using zein,
Artemisia argyi essence (AAE) and Pluronic F127 as raw materials. Then, AAE@ZMs emulsion and
film-forming agent caprolactam modified casein were mixed and applied to leather finishing. The results
show that zein interacted with F127, AAE and glutaral through chemical crosslinking and hydrogen
bonding. Meanwhile, F127 and AAE could rearrange amino acids in zein and cause fluorescence quenching.
The prepared AAE@ZMs emulsion had good dispersibility and stability with an average particle size of
about 298.6 nm when the masses of zein and AAE were 0.1 g and 0.01 g, respectively. The encapsulation
and loading efficiency of AAE@ZMs emulsion could reach 73.2% and 5.8%, and the accumulative release
rate was about 83.1% after releasing for 120 h. After the AAE@ZMs emulsion was used for leather
finishing, the release cycle of AAE in the finished leather was 6 weeks. Moreover, the finished leather
samples showed good inhibitory effect on Staphylococcus aureus and Escherichia coli, and possessed
expected mechanical properties.
Key words: zein; Artemisia argyi essence; anti-solvent method; fragrance release; microcapsules; leather
chemicals

收稿日期：2020-12-21; 定用日期：2021-01-25; DOI: 10.13550/j.jxhg.20201200
基金项目：国家自然科学基金面上项目（22078185）；陕西省创新人才推进计划青年科技新星项目（2019KJXX-011）；陕西省轻化工
助剂化学与技术协同创新中心开放基金项目（XTKF-2019-02）；国家级大学生创新创业训练计划（201910708021）
作者简介：徐群娜（1987—），女，副教授，硕士生导师，E-mail：xxqqnn870304@163.com。