Page 222 - 《精细化工》2022年第4期

·858· 精细化工 FINE CHEMICALS 第 39 卷

硫代苯并噻唑自由基吸附于铂表面，其 S—Pt 氢键电 意义。以其他种类季铵盐为烷基源，采用电化学方
子云密度如图 5c 所示。物种Ⅳ是 MTBT 吸附于铂表 法实现硫醇类底物中硫原子烷基化的反应值得进一
面，其 S—Pt 氢键电子云密度如图 5d 所示。从吸附位 步研究，以期用低价的原料和方法获得丰富的硫醚
点与铂之间存在电子云可知，吸附物确与铂之间发生 类化合物。
了稳固的吸附，即路径 c 中节点物种的存在合理。
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