Page 185 - 《精细化工）》2023年第10期

第 10 期 赵世丽，等: 异山梨醇焦油还原制备 Co-Mo 2 C 催化合成 2,5-二羟基对苯二甲酸二甲酯 ·2263·

3 结论 molybdenum carbide/carbon as hydrogen evolution electrocatalyst[J].
CIESC Journal (化工学报), 2020, 71(6): 2840-2849.
[11] LIU J, HODES G, YAN J Q, et al. Metal-doped Mo 2C (metal = Fe,
异山梨醇焦油在 850 ℃下将四水合钼酸铵和
Co, Ni, Cu) as catalysts on TiO 2 for photocatalytic hydrogen
六水合硝酸钴原位还原，制得了比表面积为 134 evolution in neutral solution[J]. Chinese Journal of Catalysis, 2021,
2
m /g 的 Co-Mo 2 C。 42(1): 205-216.
[12] LI X Y (李晓芸), MA D (马丁), BAO X H (包信和). Synthesis of
Co 与 Mo 2 C 间存在协同催化作用，n(Co)︰ molybdenum carbide catalysts over different carbon supports[J].
n(Mo)=1︰5 较好。原位还原 4 h 所制得的 Co-5Mo 2C-4 Chinese Journal of Catalysis (催化学报), 2008, 29(9): 884-888.
催化剂性能最好。反应温度影响较大，过高的温度 [13] ZHU Q L (朱全力), ZHAO X T (赵旭涛), ZHAO Z (赵振), et al.
Preparation of supported molybdenum carbide catalyst using
导致目标产物收率下降。2.00 g Co-5Mo 2 C-4 用于催 n-hexane and its hydrodesulfurization activity[J]. Chinese Journal of
化 O 2 氧化 DMSS 合成 DMDHT 的适宜反应条件是在 Catalysis (催化学报), 2005, 26(12): 1047-1052.
[14] LEI C S, ZHOU W, SHEN L J, et al. Enhanced selective H 2S
110 ℃、1.00 MPa O 2 下反应 4 h，可得到收率为 oxidation performance on Mo 2C-modified g-C 3N 4[J]. ACS Sustainable
88.22%、纯度为 99.98%的 DMDHT。催化剂循环 6 Chemistry & Engineering, 2019, 7(19): 16257-16263.
次，DMDHT 的收率仅下降 1.7%；循环 9 次，DMDHT [15] ZHAO Y H, LI S G, SUN Y H. Ni-doping effects on carbon diffusion
and oxidation over Mo 2C surfaces[J]. Journal of Physical Chemistry
的收率下降了 7.3%。 C, 2013, 117(37): 18936-18946.
本文提出的异山梨醇焦油高温原位还原法能低 [16] ZHU Q L (朱全力), YANG J (杨建), JI S F (季生福), et al. Study on
the Mo 2C/Al 2O 3 catalyst for the partial oxidation of methane to
成本地制备高比表面积的 Mo 2 C，具有一定的工业应
synthesis gas[J]. Journal of Molecular Catalysis (分子催化), 2003,
用前景，同时也为异山梨醇焦油的资源化利用提供 17(2): 118-123.
了途径。 [17] PFUND A H. The optical properties of metallic and crystalline
powders[J]. Journal of the Optical Society of America, 1933, 23(10):
参考文献： 375-377.
[18] VOLPE L, BOUDART M. Compounds of molybdenum and tungsten
[1] SUNG B, PANDEY M K, NAKAJIMA Y, et al. Identification of a with high specific surface area: Ⅱ. Carbides[J]. Journal of Solid
novel blocker of Ⅰ kappa B alpha kinase activation that enhances State Chemistry, 1985, 59(3): 348-356.
apoptosis and inhibits proliferation and invasion by suppressing [19] KIM J H, KIM K L. A study of preparation of tungsten nitride
nuclear factor-kappa B[J]. Molecular Cancer Therapeutics, 2008, catalysts with high surface area[J]. Applied Catalysis A: General,
7(1): 191-201. 1999, 181(1): 103-111.
[2] WANG S W, WANG L J, ZHU Z Q, et al. All organic sodium-ion [20] MIYAO T, SHISHIKURA I, MATSUOKA M, et al. CVD synthesis
batteries with Na 4C 8H 2O 6[J]. Angewandte Chemie International of alumina-supported molybdenum carbide catalyst[J]. Chemistry
Edition, 2014, 53(23): 5892-5896. Letters, 1996, 121(7): 561-562.
[3] WANG Y, SONG Y J, ZHAO L, et al. An investigation of the high [21] MORDENTI D, BRODZKI D, DJEGA-MARIADASSOU G. New
performance of a novel type of benzobisoxazole fiber based on synthesis of Mo 2C 14 nm in average size supported on a high specific
3,3-diaminobenzidine[J]. Polymers, 2016, 8(12): 420-431.
[4] SHORT G N, NGUYEN H T H, SCHEURLE I, et al. Aromatic surface area carbon material[J]. Journal of Solid State Chemistry,
polyesters from biosuccinic acid[J]. Polymer Chemistry, 2018, 9(30): 1998, 141(1): 114-120.
4113-4119. [22] WU W C (吴维成). Studies on supported molybdenum carbide
[5] ZHOU W, WU H, TANER Y. Enhanced H 2 adsorption in isostructural catalysts: Preparation, characterization and selective hydrogenation
metal-organic frameworks with open metal sites[J]. Journal of the [D]. Dalian: Dalian Institute of Chemical Physics, Chinese Academy
American Chemical Society, 2008, 130(46): 15268-15269. of Sciences (中国科学院大连化学物理研究所), 2004.
[6] FU X W (付兴伟), XU W (许伟), FAN X N (范新年), et al. [23] SHI J, SHAN Y H, TIAN Y, et al. Hydrophilic sulfonic acid-
Research status and development trend of PIPD fiber[J]. Technology functionalized microbead silica for dehydration of sorbitol to
Innovation and Application (科技创新与应用), 2021, 11: 63-67. isosorbide[J]. RSC Advances, 2016, 6(16): 13514-13521.
[7] SUN S (孙硕), HUANG Y D (黄玉东), LIN H (林宏), et al. Study [24] LIAO C J, LI X, YAO K Y, et al. Efficient oxidative dehydrogenation
on the synthesis of 2,5-dihydroxyterephthalic acid[J]. Chemistry and of n-heterocycles over nitrogen-doped carbon-supported cobalt
Adhesion (化学与粘合), 2007, 29(6): 413-415. nanoparticles[J]. ACS Sustainable Chemistry & Engineering. 2019,
[8] ZHANG S C ( 张首才 ), LIN X F ( 林险峰 ). Synthesis and 7(16), 13646-13654.
characterization of 2,5-dihydroxyterephthalic acid[J]. Jilin Normal [25] TIAN B L (田丙伦), LIU H M (刘红梅), SU L L (苏玲玲), et al.
University Journal (吉林师范大学学报), 2013, 34(4): 8-11. Methane dehydro-aromatization over Co-modified Mo/MCM-22
[9] STEEMERS L, WANNER M J, LUTZ M, et al. Synthesis of spiro catalysts in the absence of oxygen and coke deposition[J]. Chinese
quasi catenanes and quasi rotaxanes via a templated backfolding Journal of Catalysis (催化学报), 2001, 22: 124-128.
strategy[J]. Nature Communication, 2017, 8: 15392. [26] MASUO R, OHMORI K, HINTERMANN L, et al. First stereoselective
[10] FAN X M (范小明), CHEN X K (陈希奎), WANG Z H (汪子涵), total synthesis of FD-594 aglycon[J]. Angewandte Chemie International
et al. Self-sacrificing templated preparation of nitrogen-doped Edition, 2009, 48(19): 3462-3465.