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·976·                             精细化工   FINE CHEMICALS                                 第 40 卷

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            最常使用的硅烷仍是稳定且昂贵的苯基硅烷,甚至                                 in silicone chemistry[J]. Industrial & Engineering Chemistry Research,
            在反应过程中硅烷只能还原少量的 CO 2 ,相对比较                             2022, 61(23): 7679-7698.
            便宜的硅烷如聚甲基氢硅氧烷(PMHS)作为还原                            [11]  RAYA-BARÓN Á, OÑA-BURGOS P, FERNÁNDEZ I. Iron-catalyzed
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                 MOFs 材料在各种类型的硅氢加成反应中表现
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            出巨大的研究与应用价值,但大部分研究集中在催                                 and their derivatives as emerging catalysts for electro-Fenton process
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            针对有机硅行业合成生产中常见的带官能团的硅烷                             [14]  DIN I U, USMAN M, KHAN S, et al. Prospects for a green methanol
            偶联剂、内烯烃、不饱和羰基化合物或黏性较大的                                 thermo-catalytic process from CO 2 by using MOFs based materials:
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            一些带官能团的硅烷偶联剂、内烯烃、不饱和羰基                             [15]  AHMAD  A, KHAN S, TARIQ S,  et al. Self-sacrifice MOFs for
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            活性位点周围环境要求比较复杂;(2)黏性较大的                            [16]  MA X, LIU F, HELIAN Y, et al. Current application of MOFs based
            反应体系中容易出现活性物种的流失,从而降低催                                 heterogeneous catalysts in catalyzing transesterification/esterification
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            特的催化特性受到人们的关注,通过结合 MOFs 材                          [17]  WANG T, CAO X,  JIAO L. MOFs-derived  carbon-based metal
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            从而提高反应的选择性,以达到拓宽反应底物范围                             [18]  OTUN K O, LIU X, HILDEBRANDT D. Metal-organic framework
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